Hexamethyl 13,14-dioxapenta­cyclo­[8.2.1.1(4,7).0(2,9).0(3,8)]tetra­deca-5,11-diene-1,4,5,6,11,12-hexa­carboxyl­ate

In the title compound, C(24)H(24)O(14), the stereochemistry at the cyclo­butane ring is cis-anti-cis and the –COOMe groups in the bicyclic rings are syn to each other. The mol­ecule lies on a twofold rotation axis. In the crystal, weak C—H⋯O hydrogen bonds connect mol­ecules into chains along [001],...

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Detalles Bibliográficos
Autores principales: Lough, Alan J., Jack, Kelsey, Tam, William
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3470332/
https://www.ncbi.nlm.nih.gov/pubmed/23125745
http://dx.doi.org/10.1107/S1600536812039232
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author Lough, Alan J.
Jack, Kelsey
Tam, William
author_facet Lough, Alan J.
Jack, Kelsey
Tam, William
author_sort Lough, Alan J.
collection PubMed
description In the title compound, C(24)H(24)O(14), the stereochemistry at the cyclo­butane ring is cis-anti-cis and the –COOMe groups in the bicyclic rings are syn to each other. The mol­ecule lies on a twofold rotation axis. In the crystal, weak C—H⋯O hydrogen bonds connect mol­ecules into chains along [001], forming R (2) (2)(10) rings.
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spelling pubmed-34703322012-11-02 Hexamethyl 13,14-dioxapenta­cyclo­[8.2.1.1(4,7).0(2,9).0(3,8)]tetra­deca-5,11-diene-1,4,5,6,11,12-hexa­carboxyl­ate Lough, Alan J. Jack, Kelsey Tam, William Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(24)H(24)O(14), the stereochemistry at the cyclo­butane ring is cis-anti-cis and the –COOMe groups in the bicyclic rings are syn to each other. The mol­ecule lies on a twofold rotation axis. In the crystal, weak C—H⋯O hydrogen bonds connect mol­ecules into chains along [001], forming R (2) (2)(10) rings. International Union of Crystallography 2012-09-22 /pmc/articles/PMC3470332/ /pubmed/23125745 http://dx.doi.org/10.1107/S1600536812039232 Text en © Lough et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Lough, Alan J.
Jack, Kelsey
Tam, William
Hexamethyl 13,14-dioxapenta­cyclo­[8.2.1.1(4,7).0(2,9).0(3,8)]tetra­deca-5,11-diene-1,4,5,6,11,12-hexa­carboxyl­ate
title Hexamethyl 13,14-dioxapenta­cyclo­[8.2.1.1(4,7).0(2,9).0(3,8)]tetra­deca-5,11-diene-1,4,5,6,11,12-hexa­carboxyl­ate
title_full Hexamethyl 13,14-dioxapenta­cyclo­[8.2.1.1(4,7).0(2,9).0(3,8)]tetra­deca-5,11-diene-1,4,5,6,11,12-hexa­carboxyl­ate
title_fullStr Hexamethyl 13,14-dioxapenta­cyclo­[8.2.1.1(4,7).0(2,9).0(3,8)]tetra­deca-5,11-diene-1,4,5,6,11,12-hexa­carboxyl­ate
title_full_unstemmed Hexamethyl 13,14-dioxapenta­cyclo­[8.2.1.1(4,7).0(2,9).0(3,8)]tetra­deca-5,11-diene-1,4,5,6,11,12-hexa­carboxyl­ate
title_short Hexamethyl 13,14-dioxapenta­cyclo­[8.2.1.1(4,7).0(2,9).0(3,8)]tetra­deca-5,11-diene-1,4,5,6,11,12-hexa­carboxyl­ate
title_sort hexamethyl 13,14-dioxapenta­cyclo­[8.2.1.1(4,7).0(2,9).0(3,8)]tetra­deca-5,11-diene-1,4,5,6,11,12-hexa­carboxyl­ate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3470332/
https://www.ncbi.nlm.nih.gov/pubmed/23125745
http://dx.doi.org/10.1107/S1600536812039232
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AT tamwilliam hexamethyl1314dioxapentacyclo821147029038tetradeca511diene14561112hexacarboxylate

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