(2E)-2-[1-(2-Hy­droxy-4-meth­oxy­phenyl)ethyl­idene]-N-phenyl­hydrazine­carbox­amide monohydrate

The title compound, C(16)H(17)N(3)O(3)·H(2)O, exists in the E conformation with respect to the azomethine C=N double bond. While the phenyl ring is almost coplanar with the central hydrazinecarboxamide group [dihedral angle = 14.18 (11)°], it is twisted slightly with respect to the other aromatic ri...

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Autores principales: Annie, C. F., Jacob, Jinsa Mary, Sithambaresan, M., Kurup, M. R. Prathapachandra
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3470348/
https://www.ncbi.nlm.nih.gov/pubmed/23125761
http://dx.doi.org/10.1107/S1600536812039414
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author Annie, C. F.
Jacob, Jinsa Mary
Sithambaresan, M.
Kurup, M. R. Prathapachandra
author_facet Annie, C. F.
Jacob, Jinsa Mary
Sithambaresan, M.
Kurup, M. R. Prathapachandra
author_sort Annie, C. F.
collection PubMed
description The title compound, C(16)H(17)N(3)O(3)·H(2)O, exists in the E conformation with respect to the azomethine C=N double bond. While the phenyl ring is almost coplanar with the central hydrazinecarboxamide group [dihedral angle = 14.18 (11)°], it is twisted slightly with respect to the other aromatic ring in the mol­ecule, with a dihedral angle of 22.88 (13)°. The packing is dominated by O—H⋯O, N—H⋯O and C—H⋯O hydrogen-bond inter­actions, forming a three-dimensional supra­molecular structure which is augmented by two types of C—H⋯π inter­actions. An intramolecular O—H⋯N interaction is also present in the molecule.
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spelling pubmed-34703482012-11-02 (2E)-2-[1-(2-Hy­droxy-4-meth­oxy­phenyl)ethyl­idene]-N-phenyl­hydrazine­carbox­amide monohydrate Annie, C. F. Jacob, Jinsa Mary Sithambaresan, M. Kurup, M. R. Prathapachandra Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(16)H(17)N(3)O(3)·H(2)O, exists in the E conformation with respect to the azomethine C=N double bond. While the phenyl ring is almost coplanar with the central hydrazinecarboxamide group [dihedral angle = 14.18 (11)°], it is twisted slightly with respect to the other aromatic ring in the mol­ecule, with a dihedral angle of 22.88 (13)°. The packing is dominated by O—H⋯O, N—H⋯O and C—H⋯O hydrogen-bond inter­actions, forming a three-dimensional supra­molecular structure which is augmented by two types of C—H⋯π inter­actions. An intramolecular O—H⋯N interaction is also present in the molecule. International Union of Crystallography 2012-09-22 /pmc/articles/PMC3470348/ /pubmed/23125761 http://dx.doi.org/10.1107/S1600536812039414 Text en © Annie et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Annie, C. F.
Jacob, Jinsa Mary
Sithambaresan, M.
Kurup, M. R. Prathapachandra
(2E)-2-[1-(2-Hy­droxy-4-meth­oxy­phenyl)ethyl­idene]-N-phenyl­hydrazine­carbox­amide monohydrate
title (2E)-2-[1-(2-Hy­droxy-4-meth­oxy­phenyl)ethyl­idene]-N-phenyl­hydrazine­carbox­amide monohydrate
title_full (2E)-2-[1-(2-Hy­droxy-4-meth­oxy­phenyl)ethyl­idene]-N-phenyl­hydrazine­carbox­amide monohydrate
title_fullStr (2E)-2-[1-(2-Hy­droxy-4-meth­oxy­phenyl)ethyl­idene]-N-phenyl­hydrazine­carbox­amide monohydrate
title_full_unstemmed (2E)-2-[1-(2-Hy­droxy-4-meth­oxy­phenyl)ethyl­idene]-N-phenyl­hydrazine­carbox­amide monohydrate
title_short (2E)-2-[1-(2-Hy­droxy-4-meth­oxy­phenyl)ethyl­idene]-N-phenyl­hydrazine­carbox­amide monohydrate
title_sort (2e)-2-[1-(2-hy­droxy-4-meth­oxy­phenyl)ethyl­idene]-n-phenyl­hydrazine­carbox­amide monohydrate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3470348/
https://www.ncbi.nlm.nih.gov/pubmed/23125761
http://dx.doi.org/10.1107/S1600536812039414
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