1,1,2,2-Tetra­kis[2,4-dichloro-6-(dieth­oxy­meth­yl)phen­oxy­meth­yl]ethene

In the title compound, C(50)H(60)Cl(8)O(12), the mol­ecules are disordered about an inversion center located at the mid-point of the central C=C bond. These atoms show disorder and were modelled with two different orientations with site occupancies of 0.828 (3) and 0.172 (3). The dihedral angle betw...

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Autores principales: Köysal, Yavuz, Öztürk Yildirim, Sema, Butcher, Ray J., Düğdü, Esra
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3470353/
https://www.ncbi.nlm.nih.gov/pubmed/23125766
http://dx.doi.org/10.1107/S1600536812038299
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author Köysal, Yavuz
Öztürk Yildirim, Sema
Butcher, Ray J.
Düğdü, Esra
author_facet Köysal, Yavuz
Öztürk Yildirim, Sema
Butcher, Ray J.
Düğdü, Esra
author_sort Köysal, Yavuz
collection PubMed
description In the title compound, C(50)H(60)Cl(8)O(12), the mol­ecules are disordered about an inversion center located at the mid-point of the central C=C bond. These atoms show disorder and were modelled with two different orientations with site occupancies of 0.828 (3) and 0.172 (3). The dihedral angle between the two benzene rings in the asymmetric unit is 52.80 (6)°. Intramolecular C—H⋯O and C—H⋯Cl interactions occur and the crystal packing features inversion dimers linked by pairs of C—H⋯O bonds, generating R (2) (2)(10) loops.
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spelling pubmed-34703532012-11-02 1,1,2,2-Tetra­kis[2,4-dichloro-6-(dieth­oxy­meth­yl)phen­oxy­meth­yl]ethene Köysal, Yavuz Öztürk Yildirim, Sema Butcher, Ray J. Düğdü, Esra Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(50)H(60)Cl(8)O(12), the mol­ecules are disordered about an inversion center located at the mid-point of the central C=C bond. These atoms show disorder and were modelled with two different orientations with site occupancies of 0.828 (3) and 0.172 (3). The dihedral angle between the two benzene rings in the asymmetric unit is 52.80 (6)°. Intramolecular C—H⋯O and C—H⋯Cl interactions occur and the crystal packing features inversion dimers linked by pairs of C—H⋯O bonds, generating R (2) (2)(10) loops. International Union of Crystallography 2012-09-26 /pmc/articles/PMC3470353/ /pubmed/23125766 http://dx.doi.org/10.1107/S1600536812038299 Text en © Köysal et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Köysal, Yavuz
Öztürk Yildirim, Sema
Butcher, Ray J.
Düğdü, Esra
1,1,2,2-Tetra­kis[2,4-dichloro-6-(dieth­oxy­meth­yl)phen­oxy­meth­yl]ethene
title 1,1,2,2-Tetra­kis[2,4-dichloro-6-(dieth­oxy­meth­yl)phen­oxy­meth­yl]ethene
title_full 1,1,2,2-Tetra­kis[2,4-dichloro-6-(dieth­oxy­meth­yl)phen­oxy­meth­yl]ethene
title_fullStr 1,1,2,2-Tetra­kis[2,4-dichloro-6-(dieth­oxy­meth­yl)phen­oxy­meth­yl]ethene
title_full_unstemmed 1,1,2,2-Tetra­kis[2,4-dichloro-6-(dieth­oxy­meth­yl)phen­oxy­meth­yl]ethene
title_short 1,1,2,2-Tetra­kis[2,4-dichloro-6-(dieth­oxy­meth­yl)phen­oxy­meth­yl]ethene
title_sort 1,1,2,2-tetra­kis[2,4-dichloro-6-(dieth­oxy­meth­yl)phen­oxy­meth­yl]ethene
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3470353/
https://www.ncbi.nlm.nih.gov/pubmed/23125766
http://dx.doi.org/10.1107/S1600536812038299
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