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2-Acetyl-1,1,3,3-tetra­methyl­guanidine

In the mol­ecule of the title compound, C(7)H(15)N(3)O, the central C atom is surrounded in a nearly ideal trigonal–planar geometry by three N atoms. The C—N bond lengths in the CN(3) unit are 1.3353 (13), 1.3463 (12) and 1.3541 (13) Å, indicating an inter­mediate character between a single and a do...

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Autor principal: Tiritiris, Ioannis
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3470355/
https://www.ncbi.nlm.nih.gov/pubmed/23125768
http://dx.doi.org/10.1107/S1600536812039724
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author Tiritiris, Ioannis
author_facet Tiritiris, Ioannis
author_sort Tiritiris, Ioannis
collection PubMed
description In the mol­ecule of the title compound, C(7)H(15)N(3)O, the central C atom is surrounded in a nearly ideal trigonal–planar geometry by three N atoms. The C—N bond lengths in the CN(3) unit are 1.3353 (13), 1.3463 (12) and 1.3541 (13) Å, indicating an inter­mediate character between a single and a double bond for each C—N bond. The bonds between the N atoms and the terminal C-methyl groups all have values close to that of a typical single bond [1.4526 (13)–1.4614 (14) Å]. In the crystal, the guanidine mol­ecules are connected by weak C—H⋯O and C—H⋯N hydrogen bonds, generating layers parallel to the ab plane.
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spelling pubmed-34703552012-11-02 2-Acetyl-1,1,3,3-tetra­methyl­guanidine Tiritiris, Ioannis Acta Crystallogr Sect E Struct Rep Online Organic Papers In the mol­ecule of the title compound, C(7)H(15)N(3)O, the central C atom is surrounded in a nearly ideal trigonal–planar geometry by three N atoms. The C—N bond lengths in the CN(3) unit are 1.3353 (13), 1.3463 (12) and 1.3541 (13) Å, indicating an inter­mediate character between a single and a double bond for each C—N bond. The bonds between the N atoms and the terminal C-methyl groups all have values close to that of a typical single bond [1.4526 (13)–1.4614 (14) Å]. In the crystal, the guanidine mol­ecules are connected by weak C—H⋯O and C—H⋯N hydrogen bonds, generating layers parallel to the ab plane. International Union of Crystallography 2012-09-26 /pmc/articles/PMC3470355/ /pubmed/23125768 http://dx.doi.org/10.1107/S1600536812039724 Text en © Ioannis Tiritiris 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Tiritiris, Ioannis
2-Acetyl-1,1,3,3-tetra­methyl­guanidine
title 2-Acetyl-1,1,3,3-tetra­methyl­guanidine
title_full 2-Acetyl-1,1,3,3-tetra­methyl­guanidine
title_fullStr 2-Acetyl-1,1,3,3-tetra­methyl­guanidine
title_full_unstemmed 2-Acetyl-1,1,3,3-tetra­methyl­guanidine
title_short 2-Acetyl-1,1,3,3-tetra­methyl­guanidine
title_sort 2-acetyl-1,1,3,3-tetra­methyl­guanidine
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3470355/
https://www.ncbi.nlm.nih.gov/pubmed/23125768
http://dx.doi.org/10.1107/S1600536812039724
work_keys_str_mv AT tiritirisioannis 2acetyl1133tetramethylguanidine