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2-Acetyl-1,1,3,3-tetramethylguanidine
In the molecule of the title compound, C(7)H(15)N(3)O, the central C atom is surrounded in a nearly ideal trigonal–planar geometry by three N atoms. The C—N bond lengths in the CN(3) unit are 1.3353 (13), 1.3463 (12) and 1.3541 (13) Å, indicating an intermediate character between a single and a do...
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Formato: | Online Artículo Texto |
Lenguaje: | English |
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International Union of Crystallography
2012
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3470355/ https://www.ncbi.nlm.nih.gov/pubmed/23125768 http://dx.doi.org/10.1107/S1600536812039724 |
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author | Tiritiris, Ioannis |
author_facet | Tiritiris, Ioannis |
author_sort | Tiritiris, Ioannis |
collection | PubMed |
description | In the molecule of the title compound, C(7)H(15)N(3)O, the central C atom is surrounded in a nearly ideal trigonal–planar geometry by three N atoms. The C—N bond lengths in the CN(3) unit are 1.3353 (13), 1.3463 (12) and 1.3541 (13) Å, indicating an intermediate character between a single and a double bond for each C—N bond. The bonds between the N atoms and the terminal C-methyl groups all have values close to that of a typical single bond [1.4526 (13)–1.4614 (14) Å]. In the crystal, the guanidine molecules are connected by weak C—H⋯O and C—H⋯N hydrogen bonds, generating layers parallel to the ab plane. |
format | Online Article Text |
id | pubmed-3470355 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2012 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-34703552012-11-02 2-Acetyl-1,1,3,3-tetramethylguanidine Tiritiris, Ioannis Acta Crystallogr Sect E Struct Rep Online Organic Papers In the molecule of the title compound, C(7)H(15)N(3)O, the central C atom is surrounded in a nearly ideal trigonal–planar geometry by three N atoms. The C—N bond lengths in the CN(3) unit are 1.3353 (13), 1.3463 (12) and 1.3541 (13) Å, indicating an intermediate character between a single and a double bond for each C—N bond. The bonds between the N atoms and the terminal C-methyl groups all have values close to that of a typical single bond [1.4526 (13)–1.4614 (14) Å]. In the crystal, the guanidine molecules are connected by weak C—H⋯O and C—H⋯N hydrogen bonds, generating layers parallel to the ab plane. International Union of Crystallography 2012-09-26 /pmc/articles/PMC3470355/ /pubmed/23125768 http://dx.doi.org/10.1107/S1600536812039724 Text en © Ioannis Tiritiris 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Tiritiris, Ioannis 2-Acetyl-1,1,3,3-tetramethylguanidine |
title | 2-Acetyl-1,1,3,3-tetramethylguanidine |
title_full | 2-Acetyl-1,1,3,3-tetramethylguanidine |
title_fullStr | 2-Acetyl-1,1,3,3-tetramethylguanidine |
title_full_unstemmed | 2-Acetyl-1,1,3,3-tetramethylguanidine |
title_short | 2-Acetyl-1,1,3,3-tetramethylguanidine |
title_sort | 2-acetyl-1,1,3,3-tetramethylguanidine |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3470355/ https://www.ncbi.nlm.nih.gov/pubmed/23125768 http://dx.doi.org/10.1107/S1600536812039724 |
work_keys_str_mv | AT tiritirisioannis 2acetyl1133tetramethylguanidine |