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rac-4-Chloro-2-[({2-[(3-chloro-6-hy­droxy-2,4-dimethyl­benz­yl)(meth­yl)amino]­prop­yl}(meth­yl)amino)­meth­yl]-3,5-dimethyl­phenol

The title compound, C(23)H(32)Cl(2)N(2)O(2), a potential chiral ligand for coordination chemistry, was prepared by a two-step reaction. The mol­ecule is located on a crystallographic centre of inversion. As a result, the methyl group bonded to the methyl­ene group is disordered over two equally occu...

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Detalles Bibliográficos
Autores principales: Rivera, Augusto, Pacheco, Dency José, Ríos-Motta, Jaime, Maldonado, Mauricio, Bolte, Michael
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3470356/
https://www.ncbi.nlm.nih.gov/pubmed/23125769
http://dx.doi.org/10.1107/S1600536812039694
Descripción
Sumario:The title compound, C(23)H(32)Cl(2)N(2)O(2), a potential chiral ligand for coordination chemistry, was prepared by a two-step reaction. The mol­ecule is located on a crystallographic centre of inversion. As a result, the methyl group bonded to the methyl­ene group is disordered over two equally occupied positions, sharing the same site as the H atom of the chiral C atom. As a further consequence of the crystallographic centrosymmetry, the 1,2-diamino­propane unit adopts an anti­periplanar conformation and the two benzene rings are coplanar. The central chain is in an all-trans arrangement. An intra­molecular O—H⋯N hydrogen bond makes an S(6) ring motif. A C—H⋯π inter­action links the mol­ecules into one-dimensional chains along the [001] direction.