4-Dimethyl­amino-N′-(2-hy­droxy-4-meth­oxy­benzyl­idene)benzohydrazide methanol monosolvate

The asymmetric unit of the title compound, C(17)H(19)N(3)O(3)·CH(4)O, comprises two Schiff base mol­ecules and two methanol solvent mol­ecules. The Schiff base mol­ecules are approximately planar, with r.m.s. deviations from the planes defined by the non-H atoms of 0.107 and 0.154 Å, and with dihedr...

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Detalles Bibliográficos
Autor principal: Sun, Jingya
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3470357/
https://www.ncbi.nlm.nih.gov/pubmed/23125770
http://dx.doi.org/10.1107/S1600536812039906
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author Sun, Jingya
author_facet Sun, Jingya
author_sort Sun, Jingya
collection PubMed
description The asymmetric unit of the title compound, C(17)H(19)N(3)O(3)·CH(4)O, comprises two Schiff base mol­ecules and two methanol solvent mol­ecules. The Schiff base mol­ecules are approximately planar, with r.m.s. deviations from the planes defined by the non-H atoms of 0.107 and 0.154 Å, and with dihedral angles between the benzene rings of 4.49 (15) and 8.39 (15)°, respectively. This near-planarity is assisted by the formation of intra­molecular O—H⋯N hydrogen bonds in each mol­ecule. In the crystal, the components are linked by N—H⋯O and O—H⋯O hydrogen bonds to form chains along [010].
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spelling pubmed-34703572012-11-02 4-Dimethyl­amino-N′-(2-hy­droxy-4-meth­oxy­benzyl­idene)benzohydrazide methanol monosolvate Sun, Jingya Acta Crystallogr Sect E Struct Rep Online Organic Papers The asymmetric unit of the title compound, C(17)H(19)N(3)O(3)·CH(4)O, comprises two Schiff base mol­ecules and two methanol solvent mol­ecules. The Schiff base mol­ecules are approximately planar, with r.m.s. deviations from the planes defined by the non-H atoms of 0.107 and 0.154 Å, and with dihedral angles between the benzene rings of 4.49 (15) and 8.39 (15)°, respectively. This near-planarity is assisted by the formation of intra­molecular O—H⋯N hydrogen bonds in each mol­ecule. In the crystal, the components are linked by N—H⋯O and O—H⋯O hydrogen bonds to form chains along [010]. International Union of Crystallography 2012-09-26 /pmc/articles/PMC3470357/ /pubmed/23125770 http://dx.doi.org/10.1107/S1600536812039906 Text en © Jingya Sun 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Sun, Jingya
4-Dimethyl­amino-N′-(2-hy­droxy-4-meth­oxy­benzyl­idene)benzohydrazide methanol monosolvate
title 4-Dimethyl­amino-N′-(2-hy­droxy-4-meth­oxy­benzyl­idene)benzohydrazide methanol monosolvate
title_full 4-Dimethyl­amino-N′-(2-hy­droxy-4-meth­oxy­benzyl­idene)benzohydrazide methanol monosolvate
title_fullStr 4-Dimethyl­amino-N′-(2-hy­droxy-4-meth­oxy­benzyl­idene)benzohydrazide methanol monosolvate
title_full_unstemmed 4-Dimethyl­amino-N′-(2-hy­droxy-4-meth­oxy­benzyl­idene)benzohydrazide methanol monosolvate
title_short 4-Dimethyl­amino-N′-(2-hy­droxy-4-meth­oxy­benzyl­idene)benzohydrazide methanol monosolvate
title_sort 4-dimethyl­amino-n′-(2-hy­droxy-4-meth­oxy­benzyl­idene)benzohydrazide methanol monosolvate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3470357/
https://www.ncbi.nlm.nih.gov/pubmed/23125770
http://dx.doi.org/10.1107/S1600536812039906
work_keys_str_mv AT sunjingya 4dimethylaminon2hydroxy4methoxybenzylidenebenzohydrazidemethanolmonosolvate

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