Benzyl­ammonium hexa­noate

A binary mixture of benzyl­amine and hexa­noic acid has been reacted to form the title salt, C(7)H(10)N(+)·C(6)H(11)O(2) (−). This crystal has a 1:1 stoichiometry of acid- and amine-derived species which contrasts with other related species which can have a number of other integer ratios of acid and...

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Detalles Bibliográficos
Autores principales: Wood, Mary H., Clarke, Stuart M.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3470363/
https://www.ncbi.nlm.nih.gov/pubmed/23125776
http://dx.doi.org/10.1107/S1600536812039931
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author Wood, Mary H.
Clarke, Stuart M.
author_facet Wood, Mary H.
Clarke, Stuart M.
author_sort Wood, Mary H.
collection PubMed
description A binary mixture of benzyl­amine and hexa­noic acid has been reacted to form the title salt, C(7)H(10)N(+)·C(6)H(11)O(2) (−). This crystal has a 1:1 stoichiometry of acid- and amine-derived species which contrasts with other related species which can have a number of other integer ratios of acid and amine components. The diffraction data indicate complete transfer of a proton from the acid to the amine to give the salt, comprising a cation and anion combination, with the formation of three hydrogen bonds around each ammonium group. This contrasts with other related species.
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spelling pubmed-34703632012-11-02 Benzyl­ammonium hexa­noate Wood, Mary H. Clarke, Stuart M. Acta Crystallogr Sect E Struct Rep Online Organic Papers A binary mixture of benzyl­amine and hexa­noic acid has been reacted to form the title salt, C(7)H(10)N(+)·C(6)H(11)O(2) (−). This crystal has a 1:1 stoichiometry of acid- and amine-derived species which contrasts with other related species which can have a number of other integer ratios of acid and amine components. The diffraction data indicate complete transfer of a proton from the acid to the amine to give the salt, comprising a cation and anion combination, with the formation of three hydrogen bonds around each ammonium group. This contrasts with other related species. International Union of Crystallography 2012-09-26 /pmc/articles/PMC3470363/ /pubmed/23125776 http://dx.doi.org/10.1107/S1600536812039931 Text en © Wood and Clarke 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Wood, Mary H.
Clarke, Stuart M.
Benzyl­ammonium hexa­noate
title Benzyl­ammonium hexa­noate
title_full Benzyl­ammonium hexa­noate
title_fullStr Benzyl­ammonium hexa­noate
title_full_unstemmed Benzyl­ammonium hexa­noate
title_short Benzyl­ammonium hexa­noate
title_sort benzyl­ammonium hexa­noate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3470363/
https://www.ncbi.nlm.nih.gov/pubmed/23125776
http://dx.doi.org/10.1107/S1600536812039931
work_keys_str_mv AT woodmaryh benzylammoniumhexanoate
AT clarkestuartm benzylammoniumhexanoate

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