N-{2-[2-(2-Cyano-4,6-di­nitro­phen­yl)diazen­yl]-5-(diethyl­amino)phen­yl}acetamide

The title compound, C(19)H(19)N(7)O(5), exhibits substitutional disorder of the ortho-nitro and cyano groups, with site-occupancy factors of 0.686 (7):0.314 (7). The two aromatic rings are essentially coplanar, with a dihedral angle of 6.6 (5)°. In the diethyl­amino group, the two ethyl groups lie o...

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Detalles Bibliográficos
Autor principal: Lu, Lihua
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3470364/
https://www.ncbi.nlm.nih.gov/pubmed/23125777
http://dx.doi.org/10.1107/S160053681203992X
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author Lu, Lihua
author_facet Lu, Lihua
author_sort Lu, Lihua
collection PubMed
description The title compound, C(19)H(19)N(7)O(5), exhibits substitutional disorder of the ortho-nitro and cyano groups, with site-occupancy factors of 0.686 (7):0.314 (7). The two aromatic rings are essentially coplanar, with a dihedral angle of 6.6 (5)°. In the diethyl­amino group, the two ethyl groups lie on the same side of the amino­benzene plane. An intra­molecular N—H⋯N hydrogen bond links the amino and diazenyl groups.
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spelling pubmed-34703642012-11-02 N-{2-[2-(2-Cyano-4,6-di­nitro­phen­yl)diazen­yl]-5-(diethyl­amino)phen­yl}acetamide Lu, Lihua Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(19)H(19)N(7)O(5), exhibits substitutional disorder of the ortho-nitro and cyano groups, with site-occupancy factors of 0.686 (7):0.314 (7). The two aromatic rings are essentially coplanar, with a dihedral angle of 6.6 (5)°. In the diethyl­amino group, the two ethyl groups lie on the same side of the amino­benzene plane. An intra­molecular N—H⋯N hydrogen bond links the amino and diazenyl groups. International Union of Crystallography 2012-09-26 /pmc/articles/PMC3470364/ /pubmed/23125777 http://dx.doi.org/10.1107/S160053681203992X Text en © Lihua Lu 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Lu, Lihua
N-{2-[2-(2-Cyano-4,6-di­nitro­phen­yl)diazen­yl]-5-(diethyl­amino)phen­yl}acetamide
title N-{2-[2-(2-Cyano-4,6-di­nitro­phen­yl)diazen­yl]-5-(diethyl­amino)phen­yl}acetamide
title_full N-{2-[2-(2-Cyano-4,6-di­nitro­phen­yl)diazen­yl]-5-(diethyl­amino)phen­yl}acetamide
title_fullStr N-{2-[2-(2-Cyano-4,6-di­nitro­phen­yl)diazen­yl]-5-(diethyl­amino)phen­yl}acetamide
title_full_unstemmed N-{2-[2-(2-Cyano-4,6-di­nitro­phen­yl)diazen­yl]-5-(diethyl­amino)phen­yl}acetamide
title_short N-{2-[2-(2-Cyano-4,6-di­nitro­phen­yl)diazen­yl]-5-(diethyl­amino)phen­yl}acetamide
title_sort n-{2-[2-(2-cyano-4,6-di­nitro­phen­yl)diazen­yl]-5-(diethyl­amino)phen­yl}acetamide
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3470364/
https://www.ncbi.nlm.nih.gov/pubmed/23125777
http://dx.doi.org/10.1107/S160053681203992X
work_keys_str_mv AT lulihua n222cyano46dinitrophenyldiazenyl5diethylaminophenylacetamide

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