N,N′-Dibenzyl-N′′-(2-chloro-2,2-difluoro­acet­yl)phospho­ric triamide

In the title mol­ecule, C(16)H(17)ClF(2)N(3)O(2)P, the N—H unit of the C(=O)NHP(=O) fragment adopts a syn orientation with respect to the P=O group. The two F atoms and the Cl atom of the ClF(2)C group are disordered over two sets of sites with refined occupancies of 0.605 (6) and 0.395 (6). In the...

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Detalles Bibliográficos
Autores principales: Pourayoubi, Mehrdad, Keikha, Mojtaba, Jasinski, Jerry P., Keeley, Amanda C.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3470367/
https://www.ncbi.nlm.nih.gov/pubmed/23125780
http://dx.doi.org/10.1107/S1600536812039712
Descripción
Sumario:In the title mol­ecule, C(16)H(17)ClF(2)N(3)O(2)P, the N—H unit of the C(=O)NHP(=O) fragment adopts a syn orientation with respect to the P=O group. The two F atoms and the Cl atom of the ClF(2)C group are disordered over two sets of sites with refined occupancies of 0.605 (6) and 0.395 (6). In the crystal, mol­ecules are linked via N—H⋯O=C hydrogen bonds the and the (N—H⋯)(N—H⋯)O=P group into chains along [010].

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