N,N′-Dibenzyl-N′′-(2-chloro-2,2-difluoro­acet­yl)phospho­ric triamide

In the title mol­ecule, C(16)H(17)ClF(2)N(3)O(2)P, the N—H unit of the C(=O)NHP(=O) fragment adopts a syn orientation with respect to the P=O group. The two F atoms and the Cl atom of the ClF(2)C group are disordered over two sets of sites with refined occupancies of 0.605 (6) and 0.395 (6). In the...

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Autores principales: Pourayoubi, Mehrdad, Keikha, Mojtaba, Jasinski, Jerry P., Keeley, Amanda C.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3470367/
https://www.ncbi.nlm.nih.gov/pubmed/23125780
http://dx.doi.org/10.1107/S1600536812039712
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author Pourayoubi, Mehrdad
Keikha, Mojtaba
Jasinski, Jerry P.
Keeley, Amanda C.
author_facet Pourayoubi, Mehrdad
Keikha, Mojtaba
Jasinski, Jerry P.
Keeley, Amanda C.
author_sort Pourayoubi, Mehrdad
collection PubMed
description In the title mol­ecule, C(16)H(17)ClF(2)N(3)O(2)P, the N—H unit of the C(=O)NHP(=O) fragment adopts a syn orientation with respect to the P=O group. The two F atoms and the Cl atom of the ClF(2)C group are disordered over two sets of sites with refined occupancies of 0.605 (6) and 0.395 (6). In the crystal, mol­ecules are linked via N—H⋯O=C hydrogen bonds the and the (N—H⋯)(N—H⋯)O=P group into chains along [010].
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spelling pubmed-34703672012-11-02 N,N′-Dibenzyl-N′′-(2-chloro-2,2-difluoro­acet­yl)phospho­ric triamide Pourayoubi, Mehrdad Keikha, Mojtaba Jasinski, Jerry P. Keeley, Amanda C. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title mol­ecule, C(16)H(17)ClF(2)N(3)O(2)P, the N—H unit of the C(=O)NHP(=O) fragment adopts a syn orientation with respect to the P=O group. The two F atoms and the Cl atom of the ClF(2)C group are disordered over two sets of sites with refined occupancies of 0.605 (6) and 0.395 (6). In the crystal, mol­ecules are linked via N—H⋯O=C hydrogen bonds the and the (N—H⋯)(N—H⋯)O=P group into chains along [010]. International Union of Crystallography 2012-09-26 /pmc/articles/PMC3470367/ /pubmed/23125780 http://dx.doi.org/10.1107/S1600536812039712 Text en © Pourayoubi et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Pourayoubi, Mehrdad
Keikha, Mojtaba
Jasinski, Jerry P.
Keeley, Amanda C.
N,N′-Dibenzyl-N′′-(2-chloro-2,2-difluoro­acet­yl)phospho­ric triamide
title N,N′-Dibenzyl-N′′-(2-chloro-2,2-difluoro­acet­yl)phospho­ric triamide
title_full N,N′-Dibenzyl-N′′-(2-chloro-2,2-difluoro­acet­yl)phospho­ric triamide
title_fullStr N,N′-Dibenzyl-N′′-(2-chloro-2,2-difluoro­acet­yl)phospho­ric triamide
title_full_unstemmed N,N′-Dibenzyl-N′′-(2-chloro-2,2-difluoro­acet­yl)phospho­ric triamide
title_short N,N′-Dibenzyl-N′′-(2-chloro-2,2-difluoro­acet­yl)phospho­ric triamide
title_sort n,n′-dibenzyl-n′′-(2-chloro-2,2-difluoro­acet­yl)phospho­ric triamide
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3470367/
https://www.ncbi.nlm.nih.gov/pubmed/23125780
http://dx.doi.org/10.1107/S1600536812039712
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