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N-(2,3-Dimethylphenyl)-4-methyl-N-(4-methylphenylsulfonyl)benzenesulfonamide
In the title compound, C(22)H(23)NO(4)S(2), the dihedral angles between the dimethylphenyl ring and the two methylphenyl rings are 41.19 (15) and 20.50 (17)°; the dihedral angle between the methylphenyl rings is 48.11 (14)°. The C—N—S—C torsion angles are −87.6 (2) and 77.43 (18)°. The only possi...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3470371/ https://www.ncbi.nlm.nih.gov/pubmed/23125784 http://dx.doi.org/10.1107/S1600536812039773 |
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author | Mughal, Shumaila Younas Khan, Islam Ullah Harrison, William T. A. Khan, Muneeb Hayat Tahir, Muhammad Nawaz |
author_facet | Mughal, Shumaila Younas Khan, Islam Ullah Harrison, William T. A. Khan, Muneeb Hayat Tahir, Muhammad Nawaz |
author_sort | Mughal, Shumaila Younas |
collection | PubMed |
description | In the title compound, C(22)H(23)NO(4)S(2), the dihedral angles between the dimethylphenyl ring and the two methylphenyl rings are 41.19 (15) and 20.50 (17)°; the dihedral angle between the methylphenyl rings is 48.11 (14)°. The C—N—S—C torsion angles are −87.6 (2) and 77.43 (18)°. The only possible directional interactions in the crystal are very weak C—H⋯π interactions and very weak π–π stacking between parallel methylphenyl rings [centroid-to-centroid separation = 4.010 (2) Å and slippage = 1.987 Å]. |
format | Online Article Text |
id | pubmed-3470371 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2012 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-34703712012-11-02 N-(2,3-Dimethylphenyl)-4-methyl-N-(4-methylphenylsulfonyl)benzenesulfonamide Mughal, Shumaila Younas Khan, Islam Ullah Harrison, William T. A. Khan, Muneeb Hayat Tahir, Muhammad Nawaz Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(22)H(23)NO(4)S(2), the dihedral angles between the dimethylphenyl ring and the two methylphenyl rings are 41.19 (15) and 20.50 (17)°; the dihedral angle between the methylphenyl rings is 48.11 (14)°. The C—N—S—C torsion angles are −87.6 (2) and 77.43 (18)°. The only possible directional interactions in the crystal are very weak C—H⋯π interactions and very weak π–π stacking between parallel methylphenyl rings [centroid-to-centroid separation = 4.010 (2) Å and slippage = 1.987 Å]. International Union of Crystallography 2012-09-26 /pmc/articles/PMC3470371/ /pubmed/23125784 http://dx.doi.org/10.1107/S1600536812039773 Text en © Mughal et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Mughal, Shumaila Younas Khan, Islam Ullah Harrison, William T. A. Khan, Muneeb Hayat Tahir, Muhammad Nawaz N-(2,3-Dimethylphenyl)-4-methyl-N-(4-methylphenylsulfonyl)benzenesulfonamide |
title |
N-(2,3-Dimethylphenyl)-4-methyl-N-(4-methylphenylsulfonyl)benzenesulfonamide |
title_full |
N-(2,3-Dimethylphenyl)-4-methyl-N-(4-methylphenylsulfonyl)benzenesulfonamide |
title_fullStr |
N-(2,3-Dimethylphenyl)-4-methyl-N-(4-methylphenylsulfonyl)benzenesulfonamide |
title_full_unstemmed |
N-(2,3-Dimethylphenyl)-4-methyl-N-(4-methylphenylsulfonyl)benzenesulfonamide |
title_short |
N-(2,3-Dimethylphenyl)-4-methyl-N-(4-methylphenylsulfonyl)benzenesulfonamide |
title_sort | n-(2,3-dimethylphenyl)-4-methyl-n-(4-methylphenylsulfonyl)benzenesulfonamide |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3470371/ https://www.ncbi.nlm.nih.gov/pubmed/23125784 http://dx.doi.org/10.1107/S1600536812039773 |
work_keys_str_mv | AT mughalshumailayounas n23dimethylphenyl4methyln4methylphenylsulfonylbenzenesulfonamide AT khanislamullah n23dimethylphenyl4methyln4methylphenylsulfonylbenzenesulfonamide AT harrisonwilliamta n23dimethylphenyl4methyln4methylphenylsulfonylbenzenesulfonamide AT khanmuneebhayat n23dimethylphenyl4methyln4methylphenylsulfonylbenzenesulfonamide AT tahirmuhammadnawaz n23dimethylphenyl4methyln4methylphenylsulfonylbenzenesulfonamide |