4-Meth­oxy-N-[(E)-(5-nitro­thio­phen-2-yl)methyl­idene]aniline

The title mol­ecule, C(12)H(10)N(2)O(3)S, is nonplanar with an inter­planar angle of 33.44 (7)° between the benzene and thio­phene rings. In the crystal there exist only weak inter­molecular C—H⋯O inter­actions, π–π inter­actions between the benzene rings [centroid–centroid distance = 3.7465 (14) Å]...

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Detalles Bibliográficos
Autores principales: Akbal, Tufan, Ağar, Erbil, Gümüş, Sümeyye, Erdönmez, Ahmet
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3470380/
https://www.ncbi.nlm.nih.gov/pubmed/23125793
http://dx.doi.org/10.1107/S1600536812034344
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author Akbal, Tufan
Ağar, Erbil
Gümüş, Sümeyye
Erdönmez, Ahmet
author_facet Akbal, Tufan
Ağar, Erbil
Gümüş, Sümeyye
Erdönmez, Ahmet
author_sort Akbal, Tufan
collection PubMed
description The title mol­ecule, C(12)H(10)N(2)O(3)S, is nonplanar with an inter­planar angle of 33.44 (7)° between the benzene and thio­phene rings. In the crystal there exist only weak inter­molecular C—H⋯O inter­actions, π–π inter­actions between the benzene rings [centroid–centroid distance = 3.7465 (14) Å] and X—Y⋯π inter­actions to the thio­phene and benzene rings [N⋯centroid distances = 3.718 (3) and 3.355 (3) Å, respectively]. Inter­molecular C—H⋯O inter­actions link the mol­ecules into chains parallel to the a axis.
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spelling pubmed-34703802012-11-02 4-Meth­oxy-N-[(E)-(5-nitro­thio­phen-2-yl)methyl­idene]aniline Akbal, Tufan Ağar, Erbil Gümüş, Sümeyye Erdönmez, Ahmet Acta Crystallogr Sect E Struct Rep Online Organic Papers The title mol­ecule, C(12)H(10)N(2)O(3)S, is nonplanar with an inter­planar angle of 33.44 (7)° between the benzene and thio­phene rings. In the crystal there exist only weak inter­molecular C—H⋯O inter­actions, π–π inter­actions between the benzene rings [centroid–centroid distance = 3.7465 (14) Å] and X—Y⋯π inter­actions to the thio­phene and benzene rings [N⋯centroid distances = 3.718 (3) and 3.355 (3) Å, respectively]. Inter­molecular C—H⋯O inter­actions link the mol­ecules into chains parallel to the a axis. International Union of Crystallography 2012-09-29 /pmc/articles/PMC3470380/ /pubmed/23125793 http://dx.doi.org/10.1107/S1600536812034344 Text en © Akbal et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Akbal, Tufan
Ağar, Erbil
Gümüş, Sümeyye
Erdönmez, Ahmet
4-Meth­oxy-N-[(E)-(5-nitro­thio­phen-2-yl)methyl­idene]aniline
title 4-Meth­oxy-N-[(E)-(5-nitro­thio­phen-2-yl)methyl­idene]aniline
title_full 4-Meth­oxy-N-[(E)-(5-nitro­thio­phen-2-yl)methyl­idene]aniline
title_fullStr 4-Meth­oxy-N-[(E)-(5-nitro­thio­phen-2-yl)methyl­idene]aniline
title_full_unstemmed 4-Meth­oxy-N-[(E)-(5-nitro­thio­phen-2-yl)methyl­idene]aniline
title_short 4-Meth­oxy-N-[(E)-(5-nitro­thio­phen-2-yl)methyl­idene]aniline
title_sort 4-meth­oxy-n-[(e)-(5-nitro­thio­phen-2-yl)methyl­idene]aniline
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3470380/
https://www.ncbi.nlm.nih.gov/pubmed/23125793
http://dx.doi.org/10.1107/S1600536812034344
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AT erdonmezahmet 4methoxyne5nitrothiophen2ylmethylideneaniline

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