Ethyl 2,4-dimethyl­pyrido[1,2-a]benz­imidazole-3-carboxyl­ate

The title compound, C(16)H(16)N(2)O(2), was synthesized using a novel tandem annulation reaction between 1-(1H-benzo[d]imidazol-2-yl)ethanone and ethyl (E)-4-bromo­but-2-enoate under mild conditions. The dihedral angles formed by the mean plane of the five-membered imidazole ring with the dihydro­py...

Descripción completa

Detalles Bibliográficos
Autores principales: Zhu, Ai Guo, Ma, Zhuo Ming, Li, Lin Jie, Wei, Tian Tian, Ge, Yan Qing
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3470386/
https://www.ncbi.nlm.nih.gov/pubmed/23125799
http://dx.doi.org/10.1107/S1600536812040299
_version_ 1782246268384313344
author Zhu, Ai Guo
Ma, Zhuo Ming
Li, Lin Jie
Wei, Tian Tian
Ge, Yan Qing
author_facet Zhu, Ai Guo
Ma, Zhuo Ming
Li, Lin Jie
Wei, Tian Tian
Ge, Yan Qing
author_sort Zhu, Ai Guo
collection PubMed
description The title compound, C(16)H(16)N(2)O(2), was synthesized using a novel tandem annulation reaction between 1-(1H-benzo[d]imidazol-2-yl)ethanone and ethyl (E)-4-bromo­but-2-enoate under mild conditions. The dihedral angles formed by the mean plane of the five-membered imidazole ring with the dihydro­pyridin and benzene rings are 1.54 (9) and 1.85 (9)°, respectively.
format Online
Article
Text
id pubmed-3470386
institution National Center for Biotechnology Information
language English
publishDate 2012
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-34703862012-11-02 Ethyl 2,4-dimethyl­pyrido[1,2-a]benz­imidazole-3-carboxyl­ate Zhu, Ai Guo Ma, Zhuo Ming Li, Lin Jie Wei, Tian Tian Ge, Yan Qing Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(16)H(16)N(2)O(2), was synthesized using a novel tandem annulation reaction between 1-(1H-benzo[d]imidazol-2-yl)ethanone and ethyl (E)-4-bromo­but-2-enoate under mild conditions. The dihedral angles formed by the mean plane of the five-membered imidazole ring with the dihydro­pyridin and benzene rings are 1.54 (9) and 1.85 (9)°, respectively. International Union of Crystallography 2012-09-29 /pmc/articles/PMC3470386/ /pubmed/23125799 http://dx.doi.org/10.1107/S1600536812040299 Text en © Zhu et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Zhu, Ai Guo
Ma, Zhuo Ming
Li, Lin Jie
Wei, Tian Tian
Ge, Yan Qing
Ethyl 2,4-dimethyl­pyrido[1,2-a]benz­imidazole-3-carboxyl­ate
title Ethyl 2,4-dimethyl­pyrido[1,2-a]benz­imidazole-3-carboxyl­ate
title_full Ethyl 2,4-dimethyl­pyrido[1,2-a]benz­imidazole-3-carboxyl­ate
title_fullStr Ethyl 2,4-dimethyl­pyrido[1,2-a]benz­imidazole-3-carboxyl­ate
title_full_unstemmed Ethyl 2,4-dimethyl­pyrido[1,2-a]benz­imidazole-3-carboxyl­ate
title_short Ethyl 2,4-dimethyl­pyrido[1,2-a]benz­imidazole-3-carboxyl­ate
title_sort ethyl 2,4-dimethyl­pyrido[1,2-a]benz­imidazole-3-carboxyl­ate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3470386/
https://www.ncbi.nlm.nih.gov/pubmed/23125799
http://dx.doi.org/10.1107/S1600536812040299
work_keys_str_mv AT zhuaiguo ethyl24dimethylpyrido12abenzimidazole3carboxylate
AT mazhuoming ethyl24dimethylpyrido12abenzimidazole3carboxylate
AT lilinjie ethyl24dimethylpyrido12abenzimidazole3carboxylate
AT weitiantian ethyl24dimethylpyrido12abenzimidazole3carboxylate
AT geyanqing ethyl24dimethylpyrido12abenzimidazole3carboxylate

Ejemplares similares