(Z)-3-Methyl-1-phenyl-4-[(p-tol­yl)(p-tolyl­amino)­methyl­idene]-1H-pyrazol-5(4H)-one

In the title mol­ecule, C(25)H(23)N(3)O(2), the pyrazole ring forms dihedral angles of 28.56 (7), 80.35 (7) and 31.99 (7)° with the phenyl ring, the p-tolyl ring and the p-tolyl­amino ring, respectively. The N—H group attached to the exocyclic C=C bond is in a syn arrangement with respect to the C=O...

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Autores principales: Sharma, Naresh, Vyas, Komal M., Jadeja, R. N., Kant, Rajni, Gupta, Vivek K.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3470389/
https://www.ncbi.nlm.nih.gov/pubmed/23125802
http://dx.doi.org/10.1107/S1600536812040330
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author Sharma, Naresh
Vyas, Komal M.
Jadeja, R. N.
Kant, Rajni
Gupta, Vivek K.
author_facet Sharma, Naresh
Vyas, Komal M.
Jadeja, R. N.
Kant, Rajni
Gupta, Vivek K.
author_sort Sharma, Naresh
collection PubMed
description In the title mol­ecule, C(25)H(23)N(3)O(2), the pyrazole ring forms dihedral angles of 28.56 (7), 80.35 (7) and 31.99 (7)° with the phenyl ring, the p-tolyl ring and the p-tolyl­amino ring, respectively. The N—H group attached to the exocyclic C=C bond is in a syn arrangement with respect to the C=O bond of the pyrazolone group and an intra­molecular N—H⋯O hydrogen bond is observed. In the crystal, weak C—H⋯π inter­actions link mol­ecules along [100].
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spelling pubmed-34703892012-11-02 (Z)-3-Methyl-1-phenyl-4-[(p-tol­yl)(p-tolyl­amino)­methyl­idene]-1H-pyrazol-5(4H)-one Sharma, Naresh Vyas, Komal M. Jadeja, R. N. Kant, Rajni Gupta, Vivek K. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title mol­ecule, C(25)H(23)N(3)O(2), the pyrazole ring forms dihedral angles of 28.56 (7), 80.35 (7) and 31.99 (7)° with the phenyl ring, the p-tolyl ring and the p-tolyl­amino ring, respectively. The N—H group attached to the exocyclic C=C bond is in a syn arrangement with respect to the C=O bond of the pyrazolone group and an intra­molecular N—H⋯O hydrogen bond is observed. In the crystal, weak C—H⋯π inter­actions link mol­ecules along [100]. International Union of Crystallography 2012-09-29 /pmc/articles/PMC3470389/ /pubmed/23125802 http://dx.doi.org/10.1107/S1600536812040330 Text en © Sharma et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Sharma, Naresh
Vyas, Komal M.
Jadeja, R. N.
Kant, Rajni
Gupta, Vivek K.
(Z)-3-Methyl-1-phenyl-4-[(p-tol­yl)(p-tolyl­amino)­methyl­idene]-1H-pyrazol-5(4H)-one
title (Z)-3-Methyl-1-phenyl-4-[(p-tol­yl)(p-tolyl­amino)­methyl­idene]-1H-pyrazol-5(4H)-one
title_full (Z)-3-Methyl-1-phenyl-4-[(p-tol­yl)(p-tolyl­amino)­methyl­idene]-1H-pyrazol-5(4H)-one
title_fullStr (Z)-3-Methyl-1-phenyl-4-[(p-tol­yl)(p-tolyl­amino)­methyl­idene]-1H-pyrazol-5(4H)-one
title_full_unstemmed (Z)-3-Methyl-1-phenyl-4-[(p-tol­yl)(p-tolyl­amino)­methyl­idene]-1H-pyrazol-5(4H)-one
title_short (Z)-3-Methyl-1-phenyl-4-[(p-tol­yl)(p-tolyl­amino)­methyl­idene]-1H-pyrazol-5(4H)-one
title_sort (z)-3-methyl-1-phenyl-4-[(p-tol­yl)(p-tolyl­amino)­methyl­idene]-1h-pyrazol-5(4h)-one
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3470389/
https://www.ncbi.nlm.nih.gov/pubmed/23125802
http://dx.doi.org/10.1107/S1600536812040330
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