12-(4-Meth­oxy­benzo­yl)-2-methyl­benzo[f]pyrido[1,2-a]indole-6,11-dione

In the title compound, C(25)H(17)NO(4), the indolizine fused naphthaquinone unit is approximately planar [r.m.s deviation = 0.0678 Å] and makes a dihedral angle of 57.82 (5)° with the benzene ring of the meth­oxy­benzene group. The naphtho­quinone O atoms deviate, in the same sense, from the mean pl...

Descripción completa

Detalles Bibliográficos
Autores principales: Novina, J. Josephine, Vasuki, G., Liu, Yun, Sun, Jin-Wei
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3470392/
https://www.ncbi.nlm.nih.gov/pubmed/23125805
http://dx.doi.org/10.1107/S1600536812040408
_version_ 1782246270175281152
author Novina, J. Josephine
Vasuki, G.
Liu, Yun
Sun, Jin-Wei
author_facet Novina, J. Josephine
Vasuki, G.
Liu, Yun
Sun, Jin-Wei
author_sort Novina, J. Josephine
collection PubMed
description In the title compound, C(25)H(17)NO(4), the indolizine fused naphthaquinone unit is approximately planar [r.m.s deviation = 0.0678 Å] and makes a dihedral angle of 57.82 (5)° with the benzene ring of the meth­oxy­benzene group. The naphtho­quinone O atoms deviate, in the same sense, from the mean plane of the fused six-membered rings by 0.2001 (14) and 0.0516 (14) Å. In the crystal there is π–π stacking of inversion-related pairs of mol­ecules [inter­planar spacing = 3.514 (2) Å].
format Online
Article
Text
id pubmed-3470392
institution National Center for Biotechnology Information
language English
publishDate 2012
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-34703922012-11-02 12-(4-Meth­oxy­benzo­yl)-2-methyl­benzo[f]pyrido[1,2-a]indole-6,11-dione Novina, J. Josephine Vasuki, G. Liu, Yun Sun, Jin-Wei Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(25)H(17)NO(4), the indolizine fused naphthaquinone unit is approximately planar [r.m.s deviation = 0.0678 Å] and makes a dihedral angle of 57.82 (5)° with the benzene ring of the meth­oxy­benzene group. The naphtho­quinone O atoms deviate, in the same sense, from the mean plane of the fused six-membered rings by 0.2001 (14) and 0.0516 (14) Å. In the crystal there is π–π stacking of inversion-related pairs of mol­ecules [inter­planar spacing = 3.514 (2) Å]. International Union of Crystallography 2012-09-29 /pmc/articles/PMC3470392/ /pubmed/23125805 http://dx.doi.org/10.1107/S1600536812040408 Text en © Novina et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Novina, J. Josephine
Vasuki, G.
Liu, Yun
Sun, Jin-Wei
12-(4-Meth­oxy­benzo­yl)-2-methyl­benzo[f]pyrido[1,2-a]indole-6,11-dione
title 12-(4-Meth­oxy­benzo­yl)-2-methyl­benzo[f]pyrido[1,2-a]indole-6,11-dione
title_full 12-(4-Meth­oxy­benzo­yl)-2-methyl­benzo[f]pyrido[1,2-a]indole-6,11-dione
title_fullStr 12-(4-Meth­oxy­benzo­yl)-2-methyl­benzo[f]pyrido[1,2-a]indole-6,11-dione
title_full_unstemmed 12-(4-Meth­oxy­benzo­yl)-2-methyl­benzo[f]pyrido[1,2-a]indole-6,11-dione
title_short 12-(4-Meth­oxy­benzo­yl)-2-methyl­benzo[f]pyrido[1,2-a]indole-6,11-dione
title_sort 12-(4-meth­oxy­benzo­yl)-2-methyl­benzo[f]pyrido[1,2-a]indole-6,11-dione
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3470392/
https://www.ncbi.nlm.nih.gov/pubmed/23125805
http://dx.doi.org/10.1107/S1600536812040408
work_keys_str_mv AT novinajjosephine 124methoxybenzoyl2methylbenzofpyrido12aindole611dione
AT vasukig 124methoxybenzoyl2methylbenzofpyrido12aindole611dione
AT liuyun 124methoxybenzoyl2methylbenzofpyrido12aindole611dione
AT sunjinwei 124methoxybenzoyl2methylbenzofpyrido12aindole611dione

Ejemplares similares