(2S,7S)-10-Ethyl-1,8,10,12-tetra­aza­tetra­cyclo­[8.3.1.1(8,12).0(2,7)]penta­decan-10-ium iodide

The title chiral quaternary ammonium salt, C(13)H(25)N(4) (+)·I(−), was synthesized through the Menschutkin reaction between the cage aminal (2S,7S)-1,8,10,12-tetra­aza­tetra­cyclo­[8.3.1.1(8,12).0(2,7)]penta­decane and ethyl iodide. The quaternization occurred regioselectively on the nitrogen with...

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Detalles Bibliográficos
Autores principales: Rivera, Augusto, Osorio, Héctor Jairo, Sadat-Bernal, John, Eigner, Václav, Dušek, Michal
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3470393/
https://www.ncbi.nlm.nih.gov/pubmed/23125806
http://dx.doi.org/10.1107/S1600536812040159
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author Rivera, Augusto
Osorio, Héctor Jairo
Sadat-Bernal, John
Eigner, Václav
Dušek, Michal
author_facet Rivera, Augusto
Osorio, Héctor Jairo
Sadat-Bernal, John
Eigner, Václav
Dušek, Michal
author_sort Rivera, Augusto
collection PubMed
description The title chiral quaternary ammonium salt, C(13)H(25)N(4) (+)·I(−), was synthesized through the Menschutkin reaction between the cage aminal (2S,7S)-1,8,10,12-tetra­aza­tetra­cyclo­[8.3.1.1(8,12).0(2,7)]penta­decane and ethyl iodide. The quaternization occurred regioselectively on the nitrogen with major sp3 character. The crystal structure consists of anions and cations separated by normal distances. Ions are not linked through C—H⋯I hydrogen bonds.
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spelling pubmed-34703932012-11-02 (2S,7S)-10-Ethyl-1,8,10,12-tetra­aza­tetra­cyclo­[8.3.1.1(8,12).0(2,7)]penta­decan-10-ium iodide Rivera, Augusto Osorio, Héctor Jairo Sadat-Bernal, John Eigner, Václav Dušek, Michal Acta Crystallogr Sect E Struct Rep Online Organic Papers The title chiral quaternary ammonium salt, C(13)H(25)N(4) (+)·I(−), was synthesized through the Menschutkin reaction between the cage aminal (2S,7S)-1,8,10,12-tetra­aza­tetra­cyclo­[8.3.1.1(8,12).0(2,7)]penta­decane and ethyl iodide. The quaternization occurred regioselectively on the nitrogen with major sp3 character. The crystal structure consists of anions and cations separated by normal distances. Ions are not linked through C—H⋯I hydrogen bonds. International Union of Crystallography 2012-09-29 /pmc/articles/PMC3470393/ /pubmed/23125806 http://dx.doi.org/10.1107/S1600536812040159 Text en © Rivera et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Rivera, Augusto
Osorio, Héctor Jairo
Sadat-Bernal, John
Eigner, Václav
Dušek, Michal
(2S,7S)-10-Ethyl-1,8,10,12-tetra­aza­tetra­cyclo­[8.3.1.1(8,12).0(2,7)]penta­decan-10-ium iodide
title (2S,7S)-10-Ethyl-1,8,10,12-tetra­aza­tetra­cyclo­[8.3.1.1(8,12).0(2,7)]penta­decan-10-ium iodide
title_full (2S,7S)-10-Ethyl-1,8,10,12-tetra­aza­tetra­cyclo­[8.3.1.1(8,12).0(2,7)]penta­decan-10-ium iodide
title_fullStr (2S,7S)-10-Ethyl-1,8,10,12-tetra­aza­tetra­cyclo­[8.3.1.1(8,12).0(2,7)]penta­decan-10-ium iodide
title_full_unstemmed (2S,7S)-10-Ethyl-1,8,10,12-tetra­aza­tetra­cyclo­[8.3.1.1(8,12).0(2,7)]penta­decan-10-ium iodide
title_short (2S,7S)-10-Ethyl-1,8,10,12-tetra­aza­tetra­cyclo­[8.3.1.1(8,12).0(2,7)]penta­decan-10-ium iodide
title_sort (2s,7s)-10-ethyl-1,8,10,12-tetra­aza­tetra­cyclo­[8.3.1.1(8,12).0(2,7)]penta­decan-10-ium iodide
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3470393/
https://www.ncbi.nlm.nih.gov/pubmed/23125806
http://dx.doi.org/10.1107/S1600536812040159
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