Cargando…
3-[1-(3-Hydroxybenzyl)-1H-benzimidazol-2-yl]phenol dimethyl sulfoxide monosolvate
Crystals of the title compound were obtained as a 1:1 dimethyl sulfoxide solvate, C(20)H(16)N(2)O(2)·C(2)H(6)O. The molecular conformation of the organic molecule is similar to that in the previously reported unsolvated structure [Eltayeb et al. (2009 ▶). Acta Cryst. E65, o1374–o1375]. Thus, the d...
Autores principales: | , , , , |
---|---|
Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3470402/ https://www.ncbi.nlm.nih.gov/pubmed/23125815 http://dx.doi.org/10.1107/S1600536812040275 |
_version_ | 1782246274893873152 |
---|---|
author | Quezada-Miriel, Magdalena Avila-Sorrosa, Alcives German-Acacio, Juan Manuel Reyes-Martínez, Reyna Morales-Morales, David |
author_facet | Quezada-Miriel, Magdalena Avila-Sorrosa, Alcives German-Acacio, Juan Manuel Reyes-Martínez, Reyna Morales-Morales, David |
author_sort | Quezada-Miriel, Magdalena |
collection | PubMed |
description | Crystals of the title compound were obtained as a 1:1 dimethyl sulfoxide solvate, C(20)H(16)N(2)O(2)·C(2)H(6)O. The molecular conformation of the organic molecule is similar to that in the previously reported unsolvated structure [Eltayeb et al. (2009 ▶). Acta Cryst. E65, o1374–o1375]. Thus, the dihedral angles formed by the benzimidazole moiety with the two benzene rings are 57.54 (4) and 76.22 (5)°, and the dihedral angle between the benzene rings is 89.23 (5)°. In the crystal, a three-dimensional network features O—H⋯O, O—H⋯N and O—H⋯S hydrogen bonds, as well as C—H⋯O and C—H⋯π interactions. |
format | Online Article Text |
id | pubmed-3470402 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2012 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-34704022012-11-02 3-[1-(3-Hydroxybenzyl)-1H-benzimidazol-2-yl]phenol dimethyl sulfoxide monosolvate Quezada-Miriel, Magdalena Avila-Sorrosa, Alcives German-Acacio, Juan Manuel Reyes-Martínez, Reyna Morales-Morales, David Acta Crystallogr Sect E Struct Rep Online Organic Papers Crystals of the title compound were obtained as a 1:1 dimethyl sulfoxide solvate, C(20)H(16)N(2)O(2)·C(2)H(6)O. The molecular conformation of the organic molecule is similar to that in the previously reported unsolvated structure [Eltayeb et al. (2009 ▶). Acta Cryst. E65, o1374–o1375]. Thus, the dihedral angles formed by the benzimidazole moiety with the two benzene rings are 57.54 (4) and 76.22 (5)°, and the dihedral angle between the benzene rings is 89.23 (5)°. In the crystal, a three-dimensional network features O—H⋯O, O—H⋯N and O—H⋯S hydrogen bonds, as well as C—H⋯O and C—H⋯π interactions. International Union of Crystallography 2012-09-29 /pmc/articles/PMC3470402/ /pubmed/23125815 http://dx.doi.org/10.1107/S1600536812040275 Text en © Quezada-Miriel et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Quezada-Miriel, Magdalena Avila-Sorrosa, Alcives German-Acacio, Juan Manuel Reyes-Martínez, Reyna Morales-Morales, David 3-[1-(3-Hydroxybenzyl)-1H-benzimidazol-2-yl]phenol dimethyl sulfoxide monosolvate |
title | 3-[1-(3-Hydroxybenzyl)-1H-benzimidazol-2-yl]phenol dimethyl sulfoxide monosolvate |
title_full | 3-[1-(3-Hydroxybenzyl)-1H-benzimidazol-2-yl]phenol dimethyl sulfoxide monosolvate |
title_fullStr | 3-[1-(3-Hydroxybenzyl)-1H-benzimidazol-2-yl]phenol dimethyl sulfoxide monosolvate |
title_full_unstemmed | 3-[1-(3-Hydroxybenzyl)-1H-benzimidazol-2-yl]phenol dimethyl sulfoxide monosolvate |
title_short | 3-[1-(3-Hydroxybenzyl)-1H-benzimidazol-2-yl]phenol dimethyl sulfoxide monosolvate |
title_sort | 3-[1-(3-hydroxybenzyl)-1h-benzimidazol-2-yl]phenol dimethyl sulfoxide monosolvate |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3470402/ https://www.ncbi.nlm.nih.gov/pubmed/23125815 http://dx.doi.org/10.1107/S1600536812040275 |
work_keys_str_mv | AT quezadamirielmagdalena 313hydroxybenzyl1hbenzimidazol2ylphenoldimethylsulfoxidemonosolvate AT avilasorrosaalcives 313hydroxybenzyl1hbenzimidazol2ylphenoldimethylsulfoxidemonosolvate AT germanacaciojuanmanuel 313hydroxybenzyl1hbenzimidazol2ylphenoldimethylsulfoxidemonosolvate AT reyesmartinezreyna 313hydroxybenzyl1hbenzimidazol2ylphenoldimethylsulfoxidemonosolvate AT moralesmoralesdavid 313hydroxybenzyl1hbenzimidazol2ylphenoldimethylsulfoxidemonosolvate |