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4-Nitro­anilinium p-toluene­sulfonate

In the cation of the title salt, C(6)H(7)N(2)O(2) (+)·C(7)H(7)O(3)S(−), the benzene ring makes a dihedral angle of 10.2 (2)° with the nitro group. In the crystal, the cations and anions are linked by weak N—H⋯O hydrogen bonds, forming a layer parallel to the ac plane. A weak C—H⋯O inter­action and π...

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Detalles Bibliográficos
Autores principales: Sivakumar, P. K., Krishnakumar, M., Kanagadurai, R., Chakkaravarthi, G., Mohankumar, R.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3470406/
https://www.ncbi.nlm.nih.gov/pubmed/23125819
http://dx.doi.org/10.1107/S1600536812040664
Descripción
Sumario:In the cation of the title salt, C(6)H(7)N(2)O(2) (+)·C(7)H(7)O(3)S(−), the benzene ring makes a dihedral angle of 10.2 (2)° with the nitro group. In the crystal, the cations and anions are linked by weak N—H⋯O hydrogen bonds, forming a layer parallel to the ac plane. A weak C—H⋯O inter­action and π–π inter­actions [centroid–centroid distances of 3.738 (3) and 3.748 (3) Å] also observed within the layer.