Rh(III)-catalyzed directed C–H bond amidation of ferrocenes with isocyanates

[RhCp*(OAc)(2)(H(2)O)] [Cp* = pentamethylcyclopentadienyl] catalyzed the C–H bond amidation of ferrocenes possessing directing groups with isocyanates in the presence of 2 equiv/Rh of HBF(4)·OEt(2). A variety of disubstituted ferrocenes were prepared in high yields, or excellent diastereoselectiviti...

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Detalles Bibliográficos
Autores principales: Takebayashi, Satoshi, Shizuno, Tsubasa, Otani, Takashi, Shibata, Takanori
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Beilstein-Institut 2012
Materias:
Letter
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3511021/
https://www.ncbi.nlm.nih.gov/pubmed/23209521
http://dx.doi.org/10.3762/bjoc.8.212
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author Takebayashi, Satoshi
Shizuno, Tsubasa
Otani, Takashi
Shibata, Takanori
author_facet Takebayashi, Satoshi
Shizuno, Tsubasa
Otani, Takashi
Shibata, Takanori
author_sort Takebayashi, Satoshi
collection PubMed
description [RhCp*(OAc)(2)(H(2)O)] [Cp* = pentamethylcyclopentadienyl] catalyzed the C–H bond amidation of ferrocenes possessing directing groups with isocyanates in the presence of 2 equiv/Rh of HBF(4)·OEt(2). A variety of disubstituted ferrocenes were prepared in high yields, or excellent diastereoselectivities.
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spelling pubmed-35110212012-12-03 Rh(III)-catalyzed directed C–H bond amidation of ferrocenes with isocyanates Takebayashi, Satoshi Shizuno, Tsubasa Otani, Takashi Shibata, Takanori Beilstein J Org Chem Letter [RhCp*(OAc)(2)(H(2)O)] [Cp* = pentamethylcyclopentadienyl] catalyzed the C–H bond amidation of ferrocenes possessing directing groups with isocyanates in the presence of 2 equiv/Rh of HBF(4)·OEt(2). A variety of disubstituted ferrocenes were prepared in high yields, or excellent diastereoselectivities. Beilstein-Institut 2012-10-29 /pmc/articles/PMC3511021/ /pubmed/23209521 http://dx.doi.org/10.3762/bjoc.8.212 Text en Copyright © 2012, Takebayashi et al. https://creativecommons.org/licenses/by/2.0https://www.beilstein-journals.org/bjoc/termsThis is an Open Access article under the terms of the Creative Commons Attribution License (https://creativecommons.org/licenses/by/2.0), which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited. The license is subject to the Beilstein Journal of Organic Chemistry terms and conditions: (https://www.beilstein-journals.org/bjoc/terms)
spellingShingle Letter
Takebayashi, Satoshi
Shizuno, Tsubasa
Otani, Takashi
Shibata, Takanori
Rh(III)-catalyzed directed C–H bond amidation of ferrocenes with isocyanates
title Rh(III)-catalyzed directed C–H bond amidation of ferrocenes with isocyanates
title_full Rh(III)-catalyzed directed C–H bond amidation of ferrocenes with isocyanates
title_fullStr Rh(III)-catalyzed directed C–H bond amidation of ferrocenes with isocyanates
title_full_unstemmed Rh(III)-catalyzed directed C–H bond amidation of ferrocenes with isocyanates
title_short Rh(III)-catalyzed directed C–H bond amidation of ferrocenes with isocyanates
title_sort rh(iii)-catalyzed directed c–h bond amidation of ferrocenes with isocyanates
topic Letter
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3511021/
https://www.ncbi.nlm.nih.gov/pubmed/23209521
http://dx.doi.org/10.3762/bjoc.8.212
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