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Rh(III)-catalyzed directed C–H bond amidation of ferrocenes with isocyanates

[RhCp*(OAc)(2)(H(2)O)] [Cp* = pentamethylcyclopentadienyl] catalyzed the C–H bond amidation of ferrocenes possessing directing groups with isocyanates in the presence of 2 equiv/Rh of HBF(4)·OEt(2). A variety of disubstituted ferrocenes were prepared in high yields, or excellent diastereoselectiviti...

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Detalles Bibliográficos
Autores principales:	Takebayashi, Satoshi, Shizuno, Tsubasa, Otani, Takashi, Shibata, Takanori
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	Beilstein-Institut 2012
Materias:	Letter
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3511021/ https://www.ncbi.nlm.nih.gov/pubmed/23209521 http://dx.doi.org/10.3762/bjoc.8.212

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