New efficient ligand for sub-mol % copper-catalyzed C–N cross-coupling reactions running under air

A new efficient ligand, N,N’’-dimethyldiethylene triamine (DMDETA), has been synthesized and evaluated for sub-mol % copper-catalyzed C–N cross-coupling reactions. The efficiency of the ligand was determined by kinetic methods. DMDETA proved to display efficiency similar to DMEDA and, in addition, t...

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Detalles Bibliográficos
Autores principales: Larsson, Per-Fredrik, Astvik, Peter, Norrby, Per-Ola
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Beilstein-Institut 2012
Materias:
Letter
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3511030/
https://www.ncbi.nlm.nih.gov/pubmed/23209530
http://dx.doi.org/10.3762/bjoc.8.221
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author Larsson, Per-Fredrik
Astvik, Peter
Norrby, Per-Ola
author_facet Larsson, Per-Fredrik
Astvik, Peter
Norrby, Per-Ola
author_sort Larsson, Per-Fredrik
collection PubMed
description A new efficient ligand, N,N’’-dimethyldiethylene triamine (DMDETA), has been synthesized and evaluated for sub-mol % copper-catalyzed C–N cross-coupling reactions. The efficiency of the ligand was determined by kinetic methods. DMDETA proved to display efficiency similar to DMEDA and, in addition, the resulting catalyst was tolerant to air.
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spelling pubmed-35110302012-12-03 New efficient ligand for sub-mol % copper-catalyzed C–N cross-coupling reactions running under air Larsson, Per-Fredrik Astvik, Peter Norrby, Per-Ola Beilstein J Org Chem Letter A new efficient ligand, N,N’’-dimethyldiethylene triamine (DMDETA), has been synthesized and evaluated for sub-mol % copper-catalyzed C–N cross-coupling reactions. The efficiency of the ligand was determined by kinetic methods. DMDETA proved to display efficiency similar to DMEDA and, in addition, the resulting catalyst was tolerant to air. Beilstein-Institut 2012-11-09 /pmc/articles/PMC3511030/ /pubmed/23209530 http://dx.doi.org/10.3762/bjoc.8.221 Text en Copyright © 2012, Larsson et al. https://creativecommons.org/licenses/by/2.0https://www.beilstein-journals.org/bjoc/termsThis is an Open Access article under the terms of the Creative Commons Attribution License (https://creativecommons.org/licenses/by/2.0), which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited. The license is subject to the Beilstein Journal of Organic Chemistry terms and conditions: (https://www.beilstein-journals.org/bjoc/terms)
spellingShingle Letter
Larsson, Per-Fredrik
Astvik, Peter
Norrby, Per-Ola
New efficient ligand for sub-mol % copper-catalyzed C–N cross-coupling reactions running under air
title New efficient ligand for sub-mol % copper-catalyzed C–N cross-coupling reactions running under air
title_full New efficient ligand for sub-mol % copper-catalyzed C–N cross-coupling reactions running under air
title_fullStr New efficient ligand for sub-mol % copper-catalyzed C–N cross-coupling reactions running under air
title_full_unstemmed New efficient ligand for sub-mol % copper-catalyzed C–N cross-coupling reactions running under air
title_short New efficient ligand for sub-mol % copper-catalyzed C–N cross-coupling reactions running under air
title_sort new efficient ligand for sub-mol % copper-catalyzed c–n cross-coupling reactions running under air
topic Letter
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3511030/
https://www.ncbi.nlm.nih.gov/pubmed/23209530
http://dx.doi.org/10.3762/bjoc.8.221
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AT astvikpeter newefficientligandforsubmolcoppercatalyzedcncrosscouplingreactionsrunningunderair
AT norrbyperola newefficientligandforsubmolcoppercatalyzedcncrosscouplingreactionsrunningunderair

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