N-Heterocyclic carbene–palladium(II)-1-methylimidazole complex catalyzed Mizoroki–Heck reaction of aryl chlorides with styrenes

A well-defined N-heterocyclic carbene–palladium(II)-1-methylimidazole [NHC-Pd(II)-Im] complex 1 was found to be an effective catalyst for the Mizoroki–Heck reaction of a variety of aryl chlorides with styrenes. Both activated and deactivated aryl chlorides work well to give the corresponding couplin...

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Detalles Bibliográficos
Autores principales: Gao, Ting-Ting, Jin, Ai-Ping, Shao, Li-Xiong
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Beilstein-Institut 2012
Materias:
Full Research Paper
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3511031/
https://www.ncbi.nlm.nih.gov/pubmed/23209531
http://dx.doi.org/10.3762/bjoc.8.222
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author Gao, Ting-Ting
Jin, Ai-Ping
Shao, Li-Xiong
author_facet Gao, Ting-Ting
Jin, Ai-Ping
Shao, Li-Xiong
author_sort Gao, Ting-Ting
collection PubMed
description A well-defined N-heterocyclic carbene–palladium(II)-1-methylimidazole [NHC-Pd(II)-Im] complex 1 was found to be an effective catalyst for the Mizoroki–Heck reaction of a variety of aryl chlorides with styrenes. Both activated and deactivated aryl chlorides work well to give the corresponding coupling products in good to excellent yields by using tetrabutylammonium bromide (TBAB) as the ionic liquid.
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spelling pubmed-35110312012-12-03 N-Heterocyclic carbene–palladium(II)-1-methylimidazole complex catalyzed Mizoroki–Heck reaction of aryl chlorides with styrenes Gao, Ting-Ting Jin, Ai-Ping Shao, Li-Xiong Beilstein J Org Chem Full Research Paper A well-defined N-heterocyclic carbene–palladium(II)-1-methylimidazole [NHC-Pd(II)-Im] complex 1 was found to be an effective catalyst for the Mizoroki–Heck reaction of a variety of aryl chlorides with styrenes. Both activated and deactivated aryl chlorides work well to give the corresponding coupling products in good to excellent yields by using tetrabutylammonium bromide (TBAB) as the ionic liquid. Beilstein-Institut 2012-11-12 /pmc/articles/PMC3511031/ /pubmed/23209531 http://dx.doi.org/10.3762/bjoc.8.222 Text en Copyright © 2012, Gao et al. https://creativecommons.org/licenses/by/2.0https://www.beilstein-journals.org/bjoc/termsThis is an Open Access article under the terms of the Creative Commons Attribution License (https://creativecommons.org/licenses/by/2.0), which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited. The license is subject to the Beilstein Journal of Organic Chemistry terms and conditions: (https://www.beilstein-journals.org/bjoc/terms)
spellingShingle Full Research Paper
Gao, Ting-Ting
Jin, Ai-Ping
Shao, Li-Xiong
N-Heterocyclic carbene–palladium(II)-1-methylimidazole complex catalyzed Mizoroki–Heck reaction of aryl chlorides with styrenes
title N-Heterocyclic carbene–palladium(II)-1-methylimidazole complex catalyzed Mizoroki–Heck reaction of aryl chlorides with styrenes
title_full N-Heterocyclic carbene–palladium(II)-1-methylimidazole complex catalyzed Mizoroki–Heck reaction of aryl chlorides with styrenes
title_fullStr N-Heterocyclic carbene–palladium(II)-1-methylimidazole complex catalyzed Mizoroki–Heck reaction of aryl chlorides with styrenes
title_full_unstemmed N-Heterocyclic carbene–palladium(II)-1-methylimidazole complex catalyzed Mizoroki–Heck reaction of aryl chlorides with styrenes
title_short N-Heterocyclic carbene–palladium(II)-1-methylimidazole complex catalyzed Mizoroki–Heck reaction of aryl chlorides with styrenes
title_sort n-heterocyclic carbene–palladium(ii)-1-methylimidazole complex catalyzed mizoroki–heck reaction of aryl chlorides with styrenes
topic Full Research Paper
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3511031/
https://www.ncbi.nlm.nih.gov/pubmed/23209531
http://dx.doi.org/10.3762/bjoc.8.222
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