LiNa(5)Mo(9)O(30)

The tite compound, lithium penta­sodium nona­molybdate, LiNa(5)Mo(9)O(30), was synthesized by solid-state reaction. The three-dimensional [Mo(9)O(30)](6−) framework is built up from MoO(6) octa­hedra and MoO(5) bipyramids, linked together by edges and corners. The framework delimits two types of int...

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Autores principales: Hamza, Hamadi, Ennajeh, Ines, Zid, Mohamed Faouzi, Driss, Ahmed
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Inorganic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3515084/
https://www.ncbi.nlm.nih.gov/pubmed/23284311
http://dx.doi.org/10.1107/S1600536812041876
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author Hamza, Hamadi
Ennajeh, Ines
Zid, Mohamed Faouzi
Driss, Ahmed
author_facet Hamza, Hamadi
Ennajeh, Ines
Zid, Mohamed Faouzi
Driss, Ahmed
author_sort Hamza, Hamadi
collection PubMed
description The tite compound, lithium penta­sodium nona­molybdate, LiNa(5)Mo(9)O(30), was synthesized by solid-state reaction. The three-dimensional [Mo(9)O(30)](6−) framework is built up from MoO(6) octa­hedra and MoO(5) bipyramids, linked together by edges and corners. The framework delimits two types of inter­secting tunnels running along [100] and [010] in which the Na(+) and Li(+) ions are located. The asymmetric unit contains one Mo, one Na and one Li site located on a twofold rotation axis. The crystal studied was a racemic twin with site a twin ratio of 0.51 (10):0.49 (10). Relationships between the structures of K(2)Mo(3)O(10), K(2)Mo(4)O(13), Cs(2)Mo(7)O(22), Na(6)Mo(10)O(33) and Na(6)Mo(11)O(36) compounds are discussed.
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spelling pubmed-35150842013-01-02 LiNa(5)Mo(9)O(30) Hamza, Hamadi Ennajeh, Ines Zid, Mohamed Faouzi Driss, Ahmed Acta Crystallogr Sect E Struct Rep Online Inorganic Papers The tite compound, lithium penta­sodium nona­molybdate, LiNa(5)Mo(9)O(30), was synthesized by solid-state reaction. The three-dimensional [Mo(9)O(30)](6−) framework is built up from MoO(6) octa­hedra and MoO(5) bipyramids, linked together by edges and corners. The framework delimits two types of inter­secting tunnels running along [100] and [010] in which the Na(+) and Li(+) ions are located. The asymmetric unit contains one Mo, one Na and one Li site located on a twofold rotation axis. The crystal studied was a racemic twin with site a twin ratio of 0.51 (10):0.49 (10). Relationships between the structures of K(2)Mo(3)O(10), K(2)Mo(4)O(13), Cs(2)Mo(7)O(22), Na(6)Mo(10)O(33) and Na(6)Mo(11)O(36) compounds are discussed. International Union of Crystallography 2012-10-13 /pmc/articles/PMC3515084/ /pubmed/23284311 http://dx.doi.org/10.1107/S1600536812041876 Text en © Hamza et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Inorganic Papers
Hamza, Hamadi
Ennajeh, Ines
Zid, Mohamed Faouzi
Driss, Ahmed
LiNa(5)Mo(9)O(30)
title LiNa(5)Mo(9)O(30)
title_full LiNa(5)Mo(9)O(30)
title_fullStr LiNa(5)Mo(9)O(30)
title_full_unstemmed LiNa(5)Mo(9)O(30)
title_short LiNa(5)Mo(9)O(30)
title_sort lina(5)mo(9)o(30)
topic Inorganic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3515084/
https://www.ncbi.nlm.nih.gov/pubmed/23284311
http://dx.doi.org/10.1107/S1600536812041876
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AT drissahmed lina5mo9o30

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