Tetra­amminelithium triamminelithium tris­ulfide, [Li(NH(3))(4)][Li(NH(3))(3)S(3)]

The title compound, [Li(NH(3))(4)](+)[Li(NH(3))(3)S(3)](−), an ammo­niate of the previously unknown lithium tris­ulfide, was obtained from the reaction of lithium and sulfur in liquid ammonia. The asymmetric unit consists of two crystallographically independent formula units. The [Li(NH(3))(4)](+) c...

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Detalles Bibliográficos
Autores principales: Guentner, Christian, Korber, Nikolaus
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Inorganic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3515087/
https://www.ncbi.nlm.nih.gov/pubmed/23284314
http://dx.doi.org/10.1107/S1600536812043863
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author Guentner, Christian
Korber, Nikolaus
author_facet Guentner, Christian
Korber, Nikolaus
author_sort Guentner, Christian
collection PubMed
description The title compound, [Li(NH(3))(4)](+)[Li(NH(3))(3)S(3)](−), an ammo­niate of the previously unknown lithium tris­ulfide, was obtained from the reaction of lithium and sulfur in liquid ammonia. The asymmetric unit consists of two crystallographically independent formula units. The [Li(NH(3))(4)](+) cations are close to regular LiN(4) tetra­hedra. The anions contain LiSN(3) tetra­hedra; the S—S—S bond angles are 110.43 (5) and 109.53 (5)°. In the crystal, the components are linked by multiple N—H⋯S hydrogen bonds. A weak N—H⋯N hydrogen bond is also present.
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spelling pubmed-35150872013-01-02 Tetra­amminelithium triamminelithium tris­ulfide, [Li(NH(3))(4)][Li(NH(3))(3)S(3)] Guentner, Christian Korber, Nikolaus Acta Crystallogr Sect E Struct Rep Online Inorganic Papers The title compound, [Li(NH(3))(4)](+)[Li(NH(3))(3)S(3)](−), an ammo­niate of the previously unknown lithium tris­ulfide, was obtained from the reaction of lithium and sulfur in liquid ammonia. The asymmetric unit consists of two crystallographically independent formula units. The [Li(NH(3))(4)](+) cations are close to regular LiN(4) tetra­hedra. The anions contain LiSN(3) tetra­hedra; the S—S—S bond angles are 110.43 (5) and 109.53 (5)°. In the crystal, the components are linked by multiple N—H⋯S hydrogen bonds. A weak N—H⋯N hydrogen bond is also present. International Union of Crystallography 2012-10-27 /pmc/articles/PMC3515087/ /pubmed/23284314 http://dx.doi.org/10.1107/S1600536812043863 Text en © Guentner and Korber 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Inorganic Papers
Guentner, Christian
Korber, Nikolaus
Tetra­amminelithium triamminelithium tris­ulfide, [Li(NH(3))(4)][Li(NH(3))(3)S(3)]
title Tetra­amminelithium triamminelithium tris­ulfide, [Li(NH(3))(4)][Li(NH(3))(3)S(3)]
title_full Tetra­amminelithium triamminelithium tris­ulfide, [Li(NH(3))(4)][Li(NH(3))(3)S(3)]
title_fullStr Tetra­amminelithium triamminelithium tris­ulfide, [Li(NH(3))(4)][Li(NH(3))(3)S(3)]
title_full_unstemmed Tetra­amminelithium triamminelithium tris­ulfide, [Li(NH(3))(4)][Li(NH(3))(3)S(3)]
title_short Tetra­amminelithium triamminelithium tris­ulfide, [Li(NH(3))(4)][Li(NH(3))(3)S(3)]
title_sort tetra­amminelithium triamminelithium tris­ulfide, [li(nh(3))(4)][li(nh(3))(3)s(3)]
topic Inorganic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3515087/
https://www.ncbi.nlm.nih.gov/pubmed/23284314
http://dx.doi.org/10.1107/S1600536812043863
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