Bis(chlorido)(dimethyl­sulfoxide-κO)barium(II)

The title compound, [BaCl(2)(C(2)H(6)SO)], forms a Ba(6)Cl(9) cluster in which the BaCl(2) units are connected via dimethyl­sulfoxide (DMSO) and chloride bridges. The central Cl atom of the Ba(6)Cl(9) cluster is located on a threefold inversion axis and is coordinated octa­hedrally to six barium cat...

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Detalles Bibliográficos
Autores principales: Gschwind, Fabienne, Jansen, Martin
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3515089/
https://www.ncbi.nlm.nih.gov/pubmed/23284316
http://dx.doi.org/10.1107/S160053681204069X
Descripción
Sumario:The title compound, [BaCl(2)(C(2)H(6)SO)], forms a Ba(6)Cl(9) cluster in which the BaCl(2) units are connected via dimethyl­sulfoxide (DMSO) and chloride bridges. The central Cl atom of the Ba(6)Cl(9) cluster is located on a threefold inversion axis and is coordinated octa­hedrally to six barium cations. In the crystal, the clusters are arranged in rows, which are inter­connected by the DMSO mol­ecules, forming a three-dimensional network.

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