Bis(chlorido)(dimethyl­sulfoxide-κO)barium(II)

The title compound, [BaCl(2)(C(2)H(6)SO)], forms a Ba(6)Cl(9) cluster in which the BaCl(2) units are connected via dimethyl­sulfoxide (DMSO) and chloride bridges. The central Cl atom of the Ba(6)Cl(9) cluster is located on a threefold inversion axis and is coordinated octa­hedrally to six barium cat...

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Detalles Bibliográficos
Autores principales: Gschwind, Fabienne, Jansen, Martin
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3515089/
https://www.ncbi.nlm.nih.gov/pubmed/23284316
http://dx.doi.org/10.1107/S160053681204069X
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author Gschwind, Fabienne
Jansen, Martin
author_facet Gschwind, Fabienne
Jansen, Martin
author_sort Gschwind, Fabienne
collection PubMed
description The title compound, [BaCl(2)(C(2)H(6)SO)], forms a Ba(6)Cl(9) cluster in which the BaCl(2) units are connected via dimethyl­sulfoxide (DMSO) and chloride bridges. The central Cl atom of the Ba(6)Cl(9) cluster is located on a threefold inversion axis and is coordinated octa­hedrally to six barium cations. In the crystal, the clusters are arranged in rows, which are inter­connected by the DMSO mol­ecules, forming a three-dimensional network.
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spelling pubmed-35150892013-01-02 Bis(chlorido)(dimethyl­sulfoxide-κO)barium(II) Gschwind, Fabienne Jansen, Martin Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [BaCl(2)(C(2)H(6)SO)], forms a Ba(6)Cl(9) cluster in which the BaCl(2) units are connected via dimethyl­sulfoxide (DMSO) and chloride bridges. The central Cl atom of the Ba(6)Cl(9) cluster is located on a threefold inversion axis and is coordinated octa­hedrally to six barium cations. In the crystal, the clusters are arranged in rows, which are inter­connected by the DMSO mol­ecules, forming a three-dimensional network. International Union of Crystallography 2012-10-03 /pmc/articles/PMC3515089/ /pubmed/23284316 http://dx.doi.org/10.1107/S160053681204069X Text en © Gschwind and Jansen 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Gschwind, Fabienne
Jansen, Martin
Bis(chlorido)(dimethyl­sulfoxide-κO)barium(II)
title Bis(chlorido)(dimethyl­sulfoxide-κO)barium(II)
title_full Bis(chlorido)(dimethyl­sulfoxide-κO)barium(II)
title_fullStr Bis(chlorido)(dimethyl­sulfoxide-κO)barium(II)
title_full_unstemmed Bis(chlorido)(dimethyl­sulfoxide-κO)barium(II)
title_short Bis(chlorido)(dimethyl­sulfoxide-κO)barium(II)
title_sort bis(chlorido)(dimethyl­sulfoxide-κo)barium(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3515089/
https://www.ncbi.nlm.nih.gov/pubmed/23284316
http://dx.doi.org/10.1107/S160053681204069X
work_keys_str_mv AT gschwindfabienne bischloridodimethylsulfoxidekobariumii
AT jansenmartin bischloridodimethylsulfoxidekobariumii

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