Bis(2,4,6-trimethyl­pyridinium) tetra­bromidozincate

In the title compound, (C(8)H(12)N)(2)[ZnBr(4)], the coordination geometry of the anion is approximately tetra­hedral. The Zn—Br bond lengths range from 2.3901 (19) to 2.449 (2) Å and the Br—Zn—Br angles range from 107.09 (8) to 112.48 (8)°. In the crystal, each [ZnBr(4)](2−) anion is connected to four cations through two N—H⋯Br and two C—H⋯Br hydrogen bonds, forming two-dimensional ⋯(cation)(2)⋯anion⋯(cation(2))⋯ sheets parallel to the bc plane. Within each sheet, the anions are arranged in stacks with no significant inter-anion Br⋯Br inter­actions [the shortest being > 4.3 Å], while the cations are in chains, with weak π–π stacking inter­actions [centroid–centroid distance = 3.991 Å] between cations inter­acting with the same anion.