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Bis[5-(pyridin-2-yl)pyrazine-2-carbo­nitrile-κ(2) N (4),N (5)](trifluoro­acetato-κO)silver(I)

In the asymmetric unit of the title compound, [Ag(C(10)H(6)N(4))(2)(CF(3)CO(2))], there two mononuclear but slightly different complex units. In each, two κ(2) N:N-chelating 5-(pyridin-2-yl)pyrazine-2-carbonitrile ligands surround the Ag(I) atom, giving an N(4)O square-pyramidal coordination geometr...

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Detalles Bibliográficos
Autores principales: Li, Jing, Jia, Xiao Cuan, Qi, Jun, Liu, Yuan Yuan, Ding, Yu
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3515095/
https://www.ncbi.nlm.nih.gov/pubmed/23284322
http://dx.doi.org/10.1107/S1600536812040846
Descripción
Sumario:In the asymmetric unit of the title compound, [Ag(C(10)H(6)N(4))(2)(CF(3)CO(2))], there two mononuclear but slightly different complex units. In each, two κ(2) N:N-chelating 5-(pyridin-2-yl)pyrazine-2-carbonitrile ligands surround the Ag(I) atom, giving an N(4)O square-pyramidal coordination geometry with one trifluoro­acetate O atom at the apex. The difference between the two lies in the Ag—N bond lengths: in one complex, three normal [range 2.272 (5)–2.552 (5) Å] and one long [2.706 (4) Å] and in the second, two normal [2.254 (5) and 2.290 (5) Å] and two long [2.647 (5) and 2.675 (5) Å] are present. Short inter­molecular F⋯F contacts [2.586 (4) Å] and weak π–π stacking inter­actions [minimum ring centroid separation 3.836 (5) Å] between pyridyl and pyrazinyl rings connect the complex units, forming columns which extend along the b-axis direction.