trans-Dichloridobis[dicyclo­hex­yl(2,4,6-trimethyl­phen­yl)phosphane-κP]palladium(II)

The title compound, [PdCl(2)(C(21)H(33)P)(2)], forms a monomeric complex with a trans-square-planar coordination geometry about the Pd(II) atom which lies on an inversion centre. The Pd—P bond lengths are 2.3760 (13) Å, while the Pd—Cl bond lengths are 2.3172 (14) Å. The observed structure was found...

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Detalles Bibliográficos
Autores principales: Buthelezi, Isaac, Chiririwa, Haleden, Ogutu, Hezron, Meijboom, Reinout
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3515096/
https://www.ncbi.nlm.nih.gov/pubmed/23284323
http://dx.doi.org/10.1107/S1600536812040810
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author Buthelezi, Isaac
Chiririwa, Haleden
Ogutu, Hezron
Meijboom, Reinout
author_facet Buthelezi, Isaac
Chiririwa, Haleden
Ogutu, Hezron
Meijboom, Reinout
author_sort Buthelezi, Isaac
collection PubMed
description The title compound, [PdCl(2)(C(21)H(33)P)(2)], forms a monomeric complex with a trans-square-planar coordination geometry about the Pd(II) atom which lies on an inversion centre. The Pd—P bond lengths are 2.3760 (13) Å, while the Pd—Cl bond lengths are 2.3172 (14) Å. The observed structure was found to be closely related to that of trans-dichloridobis[dicyclo­hex­yl(phen­yl)phosphane-κP]palladium(II), [PdCl(2){P(C(6)H(11))(2)(C(6)H(5))}(2)] [Burgoyne et al. (2012 ▶). Acta Cryst. E68, m404].
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spelling pubmed-35150962013-01-02 trans-Dichloridobis[dicyclo­hex­yl(2,4,6-trimethyl­phen­yl)phosphane-κP]palladium(II) Buthelezi, Isaac Chiririwa, Haleden Ogutu, Hezron Meijboom, Reinout Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [PdCl(2)(C(21)H(33)P)(2)], forms a monomeric complex with a trans-square-planar coordination geometry about the Pd(II) atom which lies on an inversion centre. The Pd—P bond lengths are 2.3760 (13) Å, while the Pd—Cl bond lengths are 2.3172 (14) Å. The observed structure was found to be closely related to that of trans-dichloridobis[dicyclo­hex­yl(phen­yl)phosphane-κP]palladium(II), [PdCl(2){P(C(6)H(11))(2)(C(6)H(5))}(2)] [Burgoyne et al. (2012 ▶). Acta Cryst. E68, m404]. International Union of Crystallography 2012-10-06 /pmc/articles/PMC3515096/ /pubmed/23284323 http://dx.doi.org/10.1107/S1600536812040810 Text en © Buthelezi et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Buthelezi, Isaac
Chiririwa, Haleden
Ogutu, Hezron
Meijboom, Reinout
trans-Dichloridobis[dicyclo­hex­yl(2,4,6-trimethyl­phen­yl)phosphane-κP]palladium(II)
title trans-Dichloridobis[dicyclo­hex­yl(2,4,6-trimethyl­phen­yl)phosphane-κP]palladium(II)
title_full trans-Dichloridobis[dicyclo­hex­yl(2,4,6-trimethyl­phen­yl)phosphane-κP]palladium(II)
title_fullStr trans-Dichloridobis[dicyclo­hex­yl(2,4,6-trimethyl­phen­yl)phosphane-κP]palladium(II)
title_full_unstemmed trans-Dichloridobis[dicyclo­hex­yl(2,4,6-trimethyl­phen­yl)phosphane-κP]palladium(II)
title_short trans-Dichloridobis[dicyclo­hex­yl(2,4,6-trimethyl­phen­yl)phosphane-κP]palladium(II)
title_sort trans-dichloridobis[dicyclo­hex­yl(2,4,6-trimethyl­phen­yl)phosphane-κp]palladium(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3515096/
https://www.ncbi.nlm.nih.gov/pubmed/23284323
http://dx.doi.org/10.1107/S1600536812040810
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AT ogutuhezron transdichloridobisdicyclohexyl246trimethylphenylphosphanekppalladiumii
AT meijboomreinout transdichloridobisdicyclohexyl246trimethylphenylphosphanekppalladiumii

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