Poly[tetra­butyl­tetra­kis­(μ(2)-hydrogen phenyl­phospho­nato)ditin(IV)]

In the title compound, [Sn(2)(C(4)H(9))(4)(C(6)H(6)PO(3))(4)](n), the basic unit is a dimer containing two symmetry-related Sn(IV) atoms bridged by two hydrogenphenylphosphonate anions. This fragment is located about an inversion center, and each Sn(IV) atom is linked to two other hydrogenphenylphos...

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Detalles Bibliográficos
Autores principales: Sarr, Modou, Diasse-Sarr, Aminata, Diop, Libasse, Molloy, Kieran C., Kociok-Kohn, Gabriele
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3515099/
https://www.ncbi.nlm.nih.gov/pubmed/23284326
http://dx.doi.org/10.1107/S1600536812040834
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author Sarr, Modou
Diasse-Sarr, Aminata
Diop, Libasse
Molloy, Kieran C.
Kociok-Kohn, Gabriele
author_facet Sarr, Modou
Diasse-Sarr, Aminata
Diop, Libasse
Molloy, Kieran C.
Kociok-Kohn, Gabriele
author_sort Sarr, Modou
collection PubMed
description In the title compound, [Sn(2)(C(4)H(9))(4)(C(6)H(6)PO(3))(4)](n), the basic unit is a dimer containing two symmetry-related Sn(IV) atoms bridged by two hydrogenphenylphosphonate anions. This fragment is located about an inversion center, and each Sn(IV) atom is linked to two other hydrogenphenylphosphonate anions, giving a layered structure parallel to (010). The coordination geometry for the Sn(IV) atoms is close to octa­hedral. The layers are connected via O—H⋯O hydrogen bonds, generating a three-dimensional network. One butyl group is disordered over two sets of sites, with occupancies of 0.49 (2) and 0.51 (2).
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spelling pubmed-35150992013-01-02 Poly[tetra­butyl­tetra­kis­(μ(2)-hydrogen phenyl­phospho­nato)ditin(IV)] Sarr, Modou Diasse-Sarr, Aminata Diop, Libasse Molloy, Kieran C. Kociok-Kohn, Gabriele Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Sn(2)(C(4)H(9))(4)(C(6)H(6)PO(3))(4)](n), the basic unit is a dimer containing two symmetry-related Sn(IV) atoms bridged by two hydrogenphenylphosphonate anions. This fragment is located about an inversion center, and each Sn(IV) atom is linked to two other hydrogenphenylphosphonate anions, giving a layered structure parallel to (010). The coordination geometry for the Sn(IV) atoms is close to octa­hedral. The layers are connected via O—H⋯O hydrogen bonds, generating a three-dimensional network. One butyl group is disordered over two sets of sites, with occupancies of 0.49 (2) and 0.51 (2). International Union of Crystallography 2012-10-06 /pmc/articles/PMC3515099/ /pubmed/23284326 http://dx.doi.org/10.1107/S1600536812040834 Text en © Sarr et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Sarr, Modou
Diasse-Sarr, Aminata
Diop, Libasse
Molloy, Kieran C.
Kociok-Kohn, Gabriele
Poly[tetra­butyl­tetra­kis­(μ(2)-hydrogen phenyl­phospho­nato)ditin(IV)]
title Poly[tetra­butyl­tetra­kis­(μ(2)-hydrogen phenyl­phospho­nato)ditin(IV)]
title_full Poly[tetra­butyl­tetra­kis­(μ(2)-hydrogen phenyl­phospho­nato)ditin(IV)]
title_fullStr Poly[tetra­butyl­tetra­kis­(μ(2)-hydrogen phenyl­phospho­nato)ditin(IV)]
title_full_unstemmed Poly[tetra­butyl­tetra­kis­(μ(2)-hydrogen phenyl­phospho­nato)ditin(IV)]
title_short Poly[tetra­butyl­tetra­kis­(μ(2)-hydrogen phenyl­phospho­nato)ditin(IV)]
title_sort poly[tetra­butyl­tetra­kis­(μ(2)-hydrogen phenyl­phospho­nato)ditin(iv)]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3515099/
https://www.ncbi.nlm.nih.gov/pubmed/23284326
http://dx.doi.org/10.1107/S1600536812040834
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