Bis[2,3,4-trimethyl-5-[(3,4,5-trimethyl-2H-pyrrol-2-yl­idene-κN)meth­yl]-1H-pyrrolato-κN]copper(II)

In the title complex, [Cu(C(15)H(19)N(2))(2)] or [Cu(L (2))] (HL is 3,3′,4,4′,5,5′-hexa­methyl­pyrromethene), the Cu(II) atom is coordinated by four N atoms [Cu—N 1.939 (2)–1.976 (2) Å] from two L ligands in a distorted tetra­hedral geometry. The mean planes of the CuN(2)C(3) metallocyclic rings for...

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Detalles Bibliográficos
Autores principales: Erdem, Sultan S., Fronczek, Frank R., Watkins, Steven F.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3515100/
https://www.ncbi.nlm.nih.gov/pubmed/23284327
http://dx.doi.org/10.1107/S1600536812040998
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author Erdem, Sultan S.
Fronczek, Frank R.
Watkins, Steven F.
author_facet Erdem, Sultan S.
Fronczek, Frank R.
Watkins, Steven F.
author_sort Erdem, Sultan S.
collection PubMed
description In the title complex, [Cu(C(15)H(19)N(2))(2)] or [Cu(L (2))] (HL is 3,3′,4,4′,5,5′-hexa­methyl­pyrromethene), the Cu(II) atom is coordinated by four N atoms [Cu—N 1.939 (2)–1.976 (2) Å] from two L ligands in a distorted tetra­hedral geometry. The mean planes of the CuN(2)C(3) metallocyclic rings form a dihedral angle of 72.73 (6)°. In the L ligands, the pyrrole rings are inclined to each other at dihedral angles of 3.03 (7) and 9.83 (7)°. The crystal packing exhibits weak inter­molecular C—H⋯π inter­actions, which form chains in [100].
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spelling pubmed-35151002013-01-02 Bis[2,3,4-trimethyl-5-[(3,4,5-trimethyl-2H-pyrrol-2-yl­idene-κN)meth­yl]-1H-pyrrolato-κN]copper(II) Erdem, Sultan S. Fronczek, Frank R. Watkins, Steven F. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [Cu(C(15)H(19)N(2))(2)] or [Cu(L (2))] (HL is 3,3′,4,4′,5,5′-hexa­methyl­pyrromethene), the Cu(II) atom is coordinated by four N atoms [Cu—N 1.939 (2)–1.976 (2) Å] from two L ligands in a distorted tetra­hedral geometry. The mean planes of the CuN(2)C(3) metallocyclic rings form a dihedral angle of 72.73 (6)°. In the L ligands, the pyrrole rings are inclined to each other at dihedral angles of 3.03 (7) and 9.83 (7)°. The crystal packing exhibits weak inter­molecular C—H⋯π inter­actions, which form chains in [100]. International Union of Crystallography 2012-10-06 /pmc/articles/PMC3515100/ /pubmed/23284327 http://dx.doi.org/10.1107/S1600536812040998 Text en © Erdem et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Erdem, Sultan S.
Fronczek, Frank R.
Watkins, Steven F.
Bis[2,3,4-trimethyl-5-[(3,4,5-trimethyl-2H-pyrrol-2-yl­idene-κN)meth­yl]-1H-pyrrolato-κN]copper(II)
title Bis[2,3,4-trimethyl-5-[(3,4,5-trimethyl-2H-pyrrol-2-yl­idene-κN)meth­yl]-1H-pyrrolato-κN]copper(II)
title_full Bis[2,3,4-trimethyl-5-[(3,4,5-trimethyl-2H-pyrrol-2-yl­idene-κN)meth­yl]-1H-pyrrolato-κN]copper(II)
title_fullStr Bis[2,3,4-trimethyl-5-[(3,4,5-trimethyl-2H-pyrrol-2-yl­idene-κN)meth­yl]-1H-pyrrolato-κN]copper(II)
title_full_unstemmed Bis[2,3,4-trimethyl-5-[(3,4,5-trimethyl-2H-pyrrol-2-yl­idene-κN)meth­yl]-1H-pyrrolato-κN]copper(II)
title_short Bis[2,3,4-trimethyl-5-[(3,4,5-trimethyl-2H-pyrrol-2-yl­idene-κN)meth­yl]-1H-pyrrolato-κN]copper(II)
title_sort bis[2,3,4-trimethyl-5-[(3,4,5-trimethyl-2h-pyrrol-2-yl­idene-κn)meth­yl]-1h-pyrrolato-κn]copper(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3515100/
https://www.ncbi.nlm.nih.gov/pubmed/23284327
http://dx.doi.org/10.1107/S1600536812040998
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AT watkinsstevenf bis234trimethyl5345trimethyl2hpyrrol2ylideneknmethyl1hpyrrolatokncopperii

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