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μ(2)-Oxalato-bis[triphenyl(thiourea-κS)tin(IV)]
The asymmetric unit of the binuclear title compound, [Sn(2)(C(2)O(4))(C(6)H(5))(6)(CH(4)N(2)S)(2)], consists of one half of the organotin(IV) molecule. The remainder is generated by a twofold rotation axis passing through the mid-point of the oxalate C—C bond. The Sn(IV) atom exhibits a distorted t...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3515101/ https://www.ncbi.nlm.nih.gov/pubmed/23284328 http://dx.doi.org/10.1107/S1600536812040706 |
Sumario: | The asymmetric unit of the binuclear title compound, [Sn(2)(C(2)O(4))(C(6)H(5))(6)(CH(4)N(2)S)(2)], consists of one half of the organotin(IV) molecule. The remainder is generated by a twofold rotation axis passing through the mid-point of the oxalate C—C bond. The Sn(IV) atom exhibits a distorted trigonal–bipyramidal coordination environment with the phenyl groups in equatorial positions and the thiourea and the monodentately bridging oxalate anion in axial positions. The molecules are linked through N—H⋯O hydrogen bonds involving the amino group of the thiourea ligand and the uncoordinating oxalate O atoms, forming layers parallel to (001). Weak C—H⋯O interactions are also present. |
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