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μ(2)-Oxalato-bis­[triphen­yl(thio­urea-κS)tin(IV)]

The asymmetric unit of the binuclear title compound, [Sn(2)(C(2)O(4))(C(6)H(5))(6)(CH(4)N(2)S)(2)], consists of one half of the organotin(IV) mol­ecule. The remainder is generated by a twofold rotation axis passing through the mid-point of the oxalate C—C bond. The Sn(IV) atom exhibits a distorted t...

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Autores principales: Sow, Yaya, Diop, Libasse, Molloy, Kieran C., Kociok-Kohn, Gabrielle
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3515101/
https://www.ncbi.nlm.nih.gov/pubmed/23284328
http://dx.doi.org/10.1107/S1600536812040706
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author Sow, Yaya
Diop, Libasse
Molloy, Kieran C.
Kociok-Kohn, Gabrielle
author_facet Sow, Yaya
Diop, Libasse
Molloy, Kieran C.
Kociok-Kohn, Gabrielle
author_sort Sow, Yaya
collection PubMed
description The asymmetric unit of the binuclear title compound, [Sn(2)(C(2)O(4))(C(6)H(5))(6)(CH(4)N(2)S)(2)], consists of one half of the organotin(IV) mol­ecule. The remainder is generated by a twofold rotation axis passing through the mid-point of the oxalate C—C bond. The Sn(IV) atom exhibits a distorted trigonal–bipyramidal coordination environment with the phenyl groups in equatorial positions and the thio­urea and the monodentately bridging oxalate anion in axial positions. The mol­ecules are linked through N—H⋯O hydrogen bonds involving the amino group of the thio­urea ligand and the uncoordinating oxalate O atoms, forming layers parallel to (001). Weak C—H⋯O inter­actions are also present.
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spelling pubmed-35151012013-01-02 μ(2)-Oxalato-bis­[triphen­yl(thio­urea-κS)tin(IV)] Sow, Yaya Diop, Libasse Molloy, Kieran C. Kociok-Kohn, Gabrielle Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The asymmetric unit of the binuclear title compound, [Sn(2)(C(2)O(4))(C(6)H(5))(6)(CH(4)N(2)S)(2)], consists of one half of the organotin(IV) mol­ecule. The remainder is generated by a twofold rotation axis passing through the mid-point of the oxalate C—C bond. The Sn(IV) atom exhibits a distorted trigonal–bipyramidal coordination environment with the phenyl groups in equatorial positions and the thio­urea and the monodentately bridging oxalate anion in axial positions. The mol­ecules are linked through N—H⋯O hydrogen bonds involving the amino group of the thio­urea ligand and the uncoordinating oxalate O atoms, forming layers parallel to (001). Weak C—H⋯O inter­actions are also present. International Union of Crystallography 2012-10-06 /pmc/articles/PMC3515101/ /pubmed/23284328 http://dx.doi.org/10.1107/S1600536812040706 Text en © Sow et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Sow, Yaya
Diop, Libasse
Molloy, Kieran C.
Kociok-Kohn, Gabrielle
μ(2)-Oxalato-bis­[triphen­yl(thio­urea-κS)tin(IV)]
title μ(2)-Oxalato-bis­[triphen­yl(thio­urea-κS)tin(IV)]
title_full μ(2)-Oxalato-bis­[triphen­yl(thio­urea-κS)tin(IV)]
title_fullStr μ(2)-Oxalato-bis­[triphen­yl(thio­urea-κS)tin(IV)]
title_full_unstemmed μ(2)-Oxalato-bis­[triphen­yl(thio­urea-κS)tin(IV)]
title_short μ(2)-Oxalato-bis­[triphen­yl(thio­urea-κS)tin(IV)]
title_sort μ(2)-oxalato-bis­[triphen­yl(thio­urea-κs)tin(iv)]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3515101/
https://www.ncbi.nlm.nih.gov/pubmed/23284328
http://dx.doi.org/10.1107/S1600536812040706
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