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μ(2)-Oxalato-bis[triphenyl(thiourea-κS)tin(IV)]
The asymmetric unit of the binuclear title compound, [Sn(2)(C(2)O(4))(C(6)H(5))(6)(CH(4)N(2)S)(2)], consists of one half of the organotin(IV) molecule. The remainder is generated by a twofold rotation axis passing through the mid-point of the oxalate C—C bond. The Sn(IV) atom exhibits a distorted t...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3515101/ https://www.ncbi.nlm.nih.gov/pubmed/23284328 http://dx.doi.org/10.1107/S1600536812040706 |
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author | Sow, Yaya Diop, Libasse Molloy, Kieran C. Kociok-Kohn, Gabrielle |
author_facet | Sow, Yaya Diop, Libasse Molloy, Kieran C. Kociok-Kohn, Gabrielle |
author_sort | Sow, Yaya |
collection | PubMed |
description | The asymmetric unit of the binuclear title compound, [Sn(2)(C(2)O(4))(C(6)H(5))(6)(CH(4)N(2)S)(2)], consists of one half of the organotin(IV) molecule. The remainder is generated by a twofold rotation axis passing through the mid-point of the oxalate C—C bond. The Sn(IV) atom exhibits a distorted trigonal–bipyramidal coordination environment with the phenyl groups in equatorial positions and the thiourea and the monodentately bridging oxalate anion in axial positions. The molecules are linked through N—H⋯O hydrogen bonds involving the amino group of the thiourea ligand and the uncoordinating oxalate O atoms, forming layers parallel to (001). Weak C—H⋯O interactions are also present. |
format | Online Article Text |
id | pubmed-3515101 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2012 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-35151012013-01-02 μ(2)-Oxalato-bis[triphenyl(thiourea-κS)tin(IV)] Sow, Yaya Diop, Libasse Molloy, Kieran C. Kociok-Kohn, Gabrielle Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The asymmetric unit of the binuclear title compound, [Sn(2)(C(2)O(4))(C(6)H(5))(6)(CH(4)N(2)S)(2)], consists of one half of the organotin(IV) molecule. The remainder is generated by a twofold rotation axis passing through the mid-point of the oxalate C—C bond. The Sn(IV) atom exhibits a distorted trigonal–bipyramidal coordination environment with the phenyl groups in equatorial positions and the thiourea and the monodentately bridging oxalate anion in axial positions. The molecules are linked through N—H⋯O hydrogen bonds involving the amino group of the thiourea ligand and the uncoordinating oxalate O atoms, forming layers parallel to (001). Weak C—H⋯O interactions are also present. International Union of Crystallography 2012-10-06 /pmc/articles/PMC3515101/ /pubmed/23284328 http://dx.doi.org/10.1107/S1600536812040706 Text en © Sow et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Sow, Yaya Diop, Libasse Molloy, Kieran C. Kociok-Kohn, Gabrielle μ(2)-Oxalato-bis[triphenyl(thiourea-κS)tin(IV)] |
title | μ(2)-Oxalato-bis[triphenyl(thiourea-κS)tin(IV)] |
title_full | μ(2)-Oxalato-bis[triphenyl(thiourea-κS)tin(IV)] |
title_fullStr | μ(2)-Oxalato-bis[triphenyl(thiourea-κS)tin(IV)] |
title_full_unstemmed | μ(2)-Oxalato-bis[triphenyl(thiourea-κS)tin(IV)] |
title_short | μ(2)-Oxalato-bis[triphenyl(thiourea-κS)tin(IV)] |
title_sort | μ(2)-oxalato-bis[triphenyl(thiourea-κs)tin(iv)] |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3515101/ https://www.ncbi.nlm.nih.gov/pubmed/23284328 http://dx.doi.org/10.1107/S1600536812040706 |
work_keys_str_mv | AT sowyaya m2oxalatobistriphenylthioureakstiniv AT dioplibasse m2oxalatobistriphenylthioureakstiniv AT molloykieranc m2oxalatobistriphenylthioureakstiniv AT kociokkohngabrielle m2oxalatobistriphenylthioureakstiniv |