Poly[(μ-1,3-thio­cyanato-κN,S)(iso­nicotin­ato-κN,O)(ethanol-κO)cadmium(II)]

In the crystal structure of the title compound, [Cd(NCS)(C(6)H(4)NO(2))(C(2)H(5)OH)](n), the Cd(2+) cation is coordinated by one N and two O atoms of two symmetry-related isonicotinate anions, one ethanol mol­ecule and two μ-1,3-bridging thio­cyanate anions in a distorted octa­hedral N(2)O(3)S geome...

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Detalles Bibliográficos
Autores principales: Neumann, Tristan, Werner, Julia, Jess, Inke, Näther, Christian
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3515102/
https://www.ncbi.nlm.nih.gov/pubmed/23284329
http://dx.doi.org/10.1107/S1600536812040913
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author Neumann, Tristan
Werner, Julia
Jess, Inke
Näther, Christian
author_facet Neumann, Tristan
Werner, Julia
Jess, Inke
Näther, Christian
author_sort Neumann, Tristan
collection PubMed
description In the crystal structure of the title compound, [Cd(NCS)(C(6)H(4)NO(2))(C(2)H(5)OH)](n), the Cd(2+) cation is coordinated by one N and two O atoms of two symmetry-related isonicotinate anions, one ethanol mol­ecule and two μ-1,3-bridging thio­cyanate anions in a distorted octa­hedral N(2)O(3)S geometry. The metal cations are μ-1,3-bridged via thio­cyanate anions into chains that are further connected into layers parallel to the ab plane by bridging isonicotinate anions. The layers are stacked along the c axis. The crystal structure is stabilized by O—H⋯O hydrogen bonds.
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spelling pubmed-35151022013-01-02 Poly[(μ-1,3-thio­cyanato-κN,S)(iso­nicotin­ato-κN,O)(ethanol-κO)cadmium(II)] Neumann, Tristan Werner, Julia Jess, Inke Näther, Christian Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the crystal structure of the title compound, [Cd(NCS)(C(6)H(4)NO(2))(C(2)H(5)OH)](n), the Cd(2+) cation is coordinated by one N and two O atoms of two symmetry-related isonicotinate anions, one ethanol mol­ecule and two μ-1,3-bridging thio­cyanate anions in a distorted octa­hedral N(2)O(3)S geometry. The metal cations are μ-1,3-bridged via thio­cyanate anions into chains that are further connected into layers parallel to the ab plane by bridging isonicotinate anions. The layers are stacked along the c axis. The crystal structure is stabilized by O—H⋯O hydrogen bonds. International Union of Crystallography 2012-10-06 /pmc/articles/PMC3515102/ /pubmed/23284329 http://dx.doi.org/10.1107/S1600536812040913 Text en © Neumann et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Neumann, Tristan
Werner, Julia
Jess, Inke
Näther, Christian
Poly[(μ-1,3-thio­cyanato-κN,S)(iso­nicotin­ato-κN,O)(ethanol-κO)cadmium(II)]
title Poly[(μ-1,3-thio­cyanato-κN,S)(iso­nicotin­ato-κN,O)(ethanol-κO)cadmium(II)]
title_full Poly[(μ-1,3-thio­cyanato-κN,S)(iso­nicotin­ato-κN,O)(ethanol-κO)cadmium(II)]
title_fullStr Poly[(μ-1,3-thio­cyanato-κN,S)(iso­nicotin­ato-κN,O)(ethanol-κO)cadmium(II)]
title_full_unstemmed Poly[(μ-1,3-thio­cyanato-κN,S)(iso­nicotin­ato-κN,O)(ethanol-κO)cadmium(II)]
title_short Poly[(μ-1,3-thio­cyanato-κN,S)(iso­nicotin­ato-κN,O)(ethanol-κO)cadmium(II)]
title_sort poly[(μ-1,3-thio­cyanato-κn,s)(iso­nicotin­ato-κn,o)(ethanol-κo)cadmium(ii)]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3515102/
https://www.ncbi.nlm.nih.gov/pubmed/23284329
http://dx.doi.org/10.1107/S1600536812040913
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