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Tetra­kis(μ-acetato-κ(2) O:O′)-bis­[(3-pyridine­carboxaldehyde-κN′)]dicopper(II)(Cu—Cu)

The binuclear title compound, [Cu(2)(CH(3)CO(2))(4)(C(6)H(5)NO)], is located about a center of inversion. The Cu(II) atoms are connected [Cu—Cu = 2.6134 (5) Å] and bridged by four acetate ligands. Their distorted octa­hedral coordination geometry is completed by a terminal pyridine N atom of a 3-pyr...

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Autores principales: Cruz-Enriquez, Adriana, Baez-Castro, Alberto, Höpfl, Herbert, Parra-Hake, Miguel, Campos-Gaxiola, Jose J.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3515103/
https://www.ncbi.nlm.nih.gov/pubmed/23284330
http://dx.doi.org/10.1107/S1600536812041074
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author Cruz-Enriquez, Adriana
Baez-Castro, Alberto
Höpfl, Herbert
Parra-Hake, Miguel
Campos-Gaxiola, Jose J.
author_facet Cruz-Enriquez, Adriana
Baez-Castro, Alberto
Höpfl, Herbert
Parra-Hake, Miguel
Campos-Gaxiola, Jose J.
author_sort Cruz-Enriquez, Adriana
collection PubMed
description The binuclear title compound, [Cu(2)(CH(3)CO(2))(4)(C(6)H(5)NO)], is located about a center of inversion. The Cu(II) atoms are connected [Cu—Cu = 2.6134 (5) Å] and bridged by four acetate ligands. Their distorted octa­hedral coordination geometry is completed by a terminal pyridine N atom of a 3-pyridincarboxaldehyde ligand. In the crystal, the complex mol­ecules are linked by C—H⋯O hydrogen bonds, forming two-dimensional networks lying parallel to the ab plane. These networks are linked via C—H⋯O hydrogen bonds involving inversion-related 3-pyridinecarboxaldehyde ligands, forming a three dimensional supra­molecular architecture.
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spelling pubmed-35151032013-01-02 Tetra­kis(μ-acetato-κ(2) O:O′)-bis­[(3-pyridine­carboxaldehyde-κN′)]dicopper(II)(Cu—Cu) Cruz-Enriquez, Adriana Baez-Castro, Alberto Höpfl, Herbert Parra-Hake, Miguel Campos-Gaxiola, Jose J. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The binuclear title compound, [Cu(2)(CH(3)CO(2))(4)(C(6)H(5)NO)], is located about a center of inversion. The Cu(II) atoms are connected [Cu—Cu = 2.6134 (5) Å] and bridged by four acetate ligands. Their distorted octa­hedral coordination geometry is completed by a terminal pyridine N atom of a 3-pyridincarboxaldehyde ligand. In the crystal, the complex mol­ecules are linked by C—H⋯O hydrogen bonds, forming two-dimensional networks lying parallel to the ab plane. These networks are linked via C—H⋯O hydrogen bonds involving inversion-related 3-pyridinecarboxaldehyde ligands, forming a three dimensional supra­molecular architecture. International Union of Crystallography 2012-10-10 /pmc/articles/PMC3515103/ /pubmed/23284330 http://dx.doi.org/10.1107/S1600536812041074 Text en © Cruz-Enriquez et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Cruz-Enriquez, Adriana
Baez-Castro, Alberto
Höpfl, Herbert
Parra-Hake, Miguel
Campos-Gaxiola, Jose J.
Tetra­kis(μ-acetato-κ(2) O:O′)-bis­[(3-pyridine­carboxaldehyde-κN′)]dicopper(II)(Cu—Cu)
title Tetra­kis(μ-acetato-κ(2) O:O′)-bis­[(3-pyridine­carboxaldehyde-κN′)]dicopper(II)(Cu—Cu)
title_full Tetra­kis(μ-acetato-κ(2) O:O′)-bis­[(3-pyridine­carboxaldehyde-κN′)]dicopper(II)(Cu—Cu)
title_fullStr Tetra­kis(μ-acetato-κ(2) O:O′)-bis­[(3-pyridine­carboxaldehyde-κN′)]dicopper(II)(Cu—Cu)
title_full_unstemmed Tetra­kis(μ-acetato-κ(2) O:O′)-bis­[(3-pyridine­carboxaldehyde-κN′)]dicopper(II)(Cu—Cu)
title_short Tetra­kis(μ-acetato-κ(2) O:O′)-bis­[(3-pyridine­carboxaldehyde-κN′)]dicopper(II)(Cu—Cu)
title_sort tetra­kis(μ-acetato-κ(2) o:o′)-bis­[(3-pyridine­carboxaldehyde-κn′)]dicopper(ii)(cu—cu)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3515103/
https://www.ncbi.nlm.nih.gov/pubmed/23284330
http://dx.doi.org/10.1107/S1600536812041074
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