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Tetrakis(μ-acetato-κ(2) O:O′)-bis[(3-pyridinecarboxaldehyde-κN′)]dicopper(II)(Cu—Cu)
The binuclear title compound, [Cu(2)(CH(3)CO(2))(4)(C(6)H(5)NO)], is located about a center of inversion. The Cu(II) atoms are connected [Cu—Cu = 2.6134 (5) Å] and bridged by four acetate ligands. Their distorted octahedral coordination geometry is completed by a terminal pyridine N atom of a 3-pyr...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3515103/ https://www.ncbi.nlm.nih.gov/pubmed/23284330 http://dx.doi.org/10.1107/S1600536812041074 |
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author | Cruz-Enriquez, Adriana Baez-Castro, Alberto Höpfl, Herbert Parra-Hake, Miguel Campos-Gaxiola, Jose J. |
author_facet | Cruz-Enriquez, Adriana Baez-Castro, Alberto Höpfl, Herbert Parra-Hake, Miguel Campos-Gaxiola, Jose J. |
author_sort | Cruz-Enriquez, Adriana |
collection | PubMed |
description | The binuclear title compound, [Cu(2)(CH(3)CO(2))(4)(C(6)H(5)NO)], is located about a center of inversion. The Cu(II) atoms are connected [Cu—Cu = 2.6134 (5) Å] and bridged by four acetate ligands. Their distorted octahedral coordination geometry is completed by a terminal pyridine N atom of a 3-pyridincarboxaldehyde ligand. In the crystal, the complex molecules are linked by C—H⋯O hydrogen bonds, forming two-dimensional networks lying parallel to the ab plane. These networks are linked via C—H⋯O hydrogen bonds involving inversion-related 3-pyridinecarboxaldehyde ligands, forming a three dimensional supramolecular architecture. |
format | Online Article Text |
id | pubmed-3515103 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2012 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-35151032013-01-02 Tetrakis(μ-acetato-κ(2) O:O′)-bis[(3-pyridinecarboxaldehyde-κN′)]dicopper(II)(Cu—Cu) Cruz-Enriquez, Adriana Baez-Castro, Alberto Höpfl, Herbert Parra-Hake, Miguel Campos-Gaxiola, Jose J. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The binuclear title compound, [Cu(2)(CH(3)CO(2))(4)(C(6)H(5)NO)], is located about a center of inversion. The Cu(II) atoms are connected [Cu—Cu = 2.6134 (5) Å] and bridged by four acetate ligands. Their distorted octahedral coordination geometry is completed by a terminal pyridine N atom of a 3-pyridincarboxaldehyde ligand. In the crystal, the complex molecules are linked by C—H⋯O hydrogen bonds, forming two-dimensional networks lying parallel to the ab plane. These networks are linked via C—H⋯O hydrogen bonds involving inversion-related 3-pyridinecarboxaldehyde ligands, forming a three dimensional supramolecular architecture. International Union of Crystallography 2012-10-10 /pmc/articles/PMC3515103/ /pubmed/23284330 http://dx.doi.org/10.1107/S1600536812041074 Text en © Cruz-Enriquez et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Cruz-Enriquez, Adriana Baez-Castro, Alberto Höpfl, Herbert Parra-Hake, Miguel Campos-Gaxiola, Jose J. Tetrakis(μ-acetato-κ(2) O:O′)-bis[(3-pyridinecarboxaldehyde-κN′)]dicopper(II)(Cu—Cu) |
title | Tetrakis(μ-acetato-κ(2)
O:O′)-bis[(3-pyridinecarboxaldehyde-κN′)]dicopper(II)(Cu—Cu) |
title_full | Tetrakis(μ-acetato-κ(2)
O:O′)-bis[(3-pyridinecarboxaldehyde-κN′)]dicopper(II)(Cu—Cu) |
title_fullStr | Tetrakis(μ-acetato-κ(2)
O:O′)-bis[(3-pyridinecarboxaldehyde-κN′)]dicopper(II)(Cu—Cu) |
title_full_unstemmed | Tetrakis(μ-acetato-κ(2)
O:O′)-bis[(3-pyridinecarboxaldehyde-κN′)]dicopper(II)(Cu—Cu) |
title_short | Tetrakis(μ-acetato-κ(2)
O:O′)-bis[(3-pyridinecarboxaldehyde-κN′)]dicopper(II)(Cu—Cu) |
title_sort | tetrakis(μ-acetato-κ(2)
o:o′)-bis[(3-pyridinecarboxaldehyde-κn′)]dicopper(ii)(cu—cu) |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3515103/ https://www.ncbi.nlm.nih.gov/pubmed/23284330 http://dx.doi.org/10.1107/S1600536812041074 |
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