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Tetra­kis(5,7-dimethyl­quinolin-8-olato-κ(2) N,O)zirconium(IV) dimethyl­form­amide disolvate

In the title compound, [Zr(C(11)H(10)NO)(4)]·2C(3)H(7)NO, the Zr(IV) ion is coordinated by four bidentate 5,7-dimethylquinolin-8-olate ligands in a slightly distorted square-anti­prismatic coordination environment. The asymmetric unit also contains two N,N′-dimethyl­formamide (DMF) solvent mol­ecule...

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Detalles Bibliográficos
Autores principales: Steyn, Maryke, Visser, Hendrik G., Roodt, Andreas
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3515106/
https://www.ncbi.nlm.nih.gov/pubmed/23284333
http://dx.doi.org/10.1107/S1600536812042092
Descripción
Sumario:In the title compound, [Zr(C(11)H(10)NO)(4)]·2C(3)H(7)NO, the Zr(IV) ion is coordinated by four bidentate 5,7-dimethylquinolin-8-olate ligands in a slightly distorted square-anti­prismatic coordination environment. The asymmetric unit also contains two N,N′-dimethyl­formamide (DMF) solvent mol­ecules. In the crystal, a weak C—H⋯O hydrogen bond links the complex mol­ecule to a solvent mol­ecule and weak π–π stacking inter­actions [centroid–centroid distance = 3.671 (3) Å] also occur. One of the DMF solvent mol­ecules was refined as disordered over three sets of sites, with refined occupancies in the ratio of 0.391 (9):0.342 (10):0.267 (7).