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Tetra­kis(5,7-dimethyl­quinolin-8-olato-κ(2) N,O)zirconium(IV) dimethyl­form­amide disolvate

In the title compound, [Zr(C(11)H(10)NO)(4)]·2C(3)H(7)NO, the Zr(IV) ion is coordinated by four bidentate 5,7-dimethylquinolin-8-olate ligands in a slightly distorted square-anti­prismatic coordination environment. The asymmetric unit also contains two N,N′-dimethyl­formamide (DMF) solvent mol­ecule...

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Detalles Bibliográficos
Autores principales: Steyn, Maryke, Visser, Hendrik G., Roodt, Andreas
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3515106/
https://www.ncbi.nlm.nih.gov/pubmed/23284333
http://dx.doi.org/10.1107/S1600536812042092
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author Steyn, Maryke
Visser, Hendrik G.
Roodt, Andreas
author_facet Steyn, Maryke
Visser, Hendrik G.
Roodt, Andreas
author_sort Steyn, Maryke
collection PubMed
description In the title compound, [Zr(C(11)H(10)NO)(4)]·2C(3)H(7)NO, the Zr(IV) ion is coordinated by four bidentate 5,7-dimethylquinolin-8-olate ligands in a slightly distorted square-anti­prismatic coordination environment. The asymmetric unit also contains two N,N′-dimethyl­formamide (DMF) solvent mol­ecules. In the crystal, a weak C—H⋯O hydrogen bond links the complex mol­ecule to a solvent mol­ecule and weak π–π stacking inter­actions [centroid–centroid distance = 3.671 (3) Å] also occur. One of the DMF solvent mol­ecules was refined as disordered over three sets of sites, with refined occupancies in the ratio of 0.391 (9):0.342 (10):0.267 (7).
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spelling pubmed-35151062013-01-02 Tetra­kis(5,7-dimethyl­quinolin-8-olato-κ(2) N,O)zirconium(IV) dimethyl­form­amide disolvate Steyn, Maryke Visser, Hendrik G. Roodt, Andreas Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Zr(C(11)H(10)NO)(4)]·2C(3)H(7)NO, the Zr(IV) ion is coordinated by four bidentate 5,7-dimethylquinolin-8-olate ligands in a slightly distorted square-anti­prismatic coordination environment. The asymmetric unit also contains two N,N′-dimethyl­formamide (DMF) solvent mol­ecules. In the crystal, a weak C—H⋯O hydrogen bond links the complex mol­ecule to a solvent mol­ecule and weak π–π stacking inter­actions [centroid–centroid distance = 3.671 (3) Å] also occur. One of the DMF solvent mol­ecules was refined as disordered over three sets of sites, with refined occupancies in the ratio of 0.391 (9):0.342 (10):0.267 (7). International Union of Crystallography 2012-10-13 /pmc/articles/PMC3515106/ /pubmed/23284333 http://dx.doi.org/10.1107/S1600536812042092 Text en © Steyn et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Steyn, Maryke
Visser, Hendrik G.
Roodt, Andreas
Tetra­kis(5,7-dimethyl­quinolin-8-olato-κ(2) N,O)zirconium(IV) dimethyl­form­amide disolvate
title Tetra­kis(5,7-dimethyl­quinolin-8-olato-κ(2) N,O)zirconium(IV) dimethyl­form­amide disolvate
title_full Tetra­kis(5,7-dimethyl­quinolin-8-olato-κ(2) N,O)zirconium(IV) dimethyl­form­amide disolvate
title_fullStr Tetra­kis(5,7-dimethyl­quinolin-8-olato-κ(2) N,O)zirconium(IV) dimethyl­form­amide disolvate
title_full_unstemmed Tetra­kis(5,7-dimethyl­quinolin-8-olato-κ(2) N,O)zirconium(IV) dimethyl­form­amide disolvate
title_short Tetra­kis(5,7-dimethyl­quinolin-8-olato-κ(2) N,O)zirconium(IV) dimethyl­form­amide disolvate
title_sort tetra­kis(5,7-dimethyl­quinolin-8-olato-κ(2) n,o)zirconium(iv) dimethyl­form­amide disolvate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3515106/
https://www.ncbi.nlm.nih.gov/pubmed/23284333
http://dx.doi.org/10.1107/S1600536812042092
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AT roodtandreas tetrakis57dimethylquinolin8olatok2nozirconiumivdimethylformamidedisolvate