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Tetrakis(5,7-dimethylquinolin-8-olato-κ(2) N,O)zirconium(IV) dimethylformamide disolvate
In the title compound, [Zr(C(11)H(10)NO)(4)]·2C(3)H(7)NO, the Zr(IV) ion is coordinated by four bidentate 5,7-dimethylquinolin-8-olate ligands in a slightly distorted square-antiprismatic coordination environment. The asymmetric unit also contains two N,N′-dimethylformamide (DMF) solvent molecule...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3515106/ https://www.ncbi.nlm.nih.gov/pubmed/23284333 http://dx.doi.org/10.1107/S1600536812042092 |
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author | Steyn, Maryke Visser, Hendrik G. Roodt, Andreas |
author_facet | Steyn, Maryke Visser, Hendrik G. Roodt, Andreas |
author_sort | Steyn, Maryke |
collection | PubMed |
description | In the title compound, [Zr(C(11)H(10)NO)(4)]·2C(3)H(7)NO, the Zr(IV) ion is coordinated by four bidentate 5,7-dimethylquinolin-8-olate ligands in a slightly distorted square-antiprismatic coordination environment. The asymmetric unit also contains two N,N′-dimethylformamide (DMF) solvent molecules. In the crystal, a weak C—H⋯O hydrogen bond links the complex molecule to a solvent molecule and weak π–π stacking interactions [centroid–centroid distance = 3.671 (3) Å] also occur. One of the DMF solvent molecules was refined as disordered over three sets of sites, with refined occupancies in the ratio of 0.391 (9):0.342 (10):0.267 (7). |
format | Online Article Text |
id | pubmed-3515106 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2012 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-35151062013-01-02 Tetrakis(5,7-dimethylquinolin-8-olato-κ(2) N,O)zirconium(IV) dimethylformamide disolvate Steyn, Maryke Visser, Hendrik G. Roodt, Andreas Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Zr(C(11)H(10)NO)(4)]·2C(3)H(7)NO, the Zr(IV) ion is coordinated by four bidentate 5,7-dimethylquinolin-8-olate ligands in a slightly distorted square-antiprismatic coordination environment. The asymmetric unit also contains two N,N′-dimethylformamide (DMF) solvent molecules. In the crystal, a weak C—H⋯O hydrogen bond links the complex molecule to a solvent molecule and weak π–π stacking interactions [centroid–centroid distance = 3.671 (3) Å] also occur. One of the DMF solvent molecules was refined as disordered over three sets of sites, with refined occupancies in the ratio of 0.391 (9):0.342 (10):0.267 (7). International Union of Crystallography 2012-10-13 /pmc/articles/PMC3515106/ /pubmed/23284333 http://dx.doi.org/10.1107/S1600536812042092 Text en © Steyn et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Steyn, Maryke Visser, Hendrik G. Roodt, Andreas Tetrakis(5,7-dimethylquinolin-8-olato-κ(2) N,O)zirconium(IV) dimethylformamide disolvate |
title | Tetrakis(5,7-dimethylquinolin-8-olato-κ(2)
N,O)zirconium(IV) dimethylformamide disolvate |
title_full | Tetrakis(5,7-dimethylquinolin-8-olato-κ(2)
N,O)zirconium(IV) dimethylformamide disolvate |
title_fullStr | Tetrakis(5,7-dimethylquinolin-8-olato-κ(2)
N,O)zirconium(IV) dimethylformamide disolvate |
title_full_unstemmed | Tetrakis(5,7-dimethylquinolin-8-olato-κ(2)
N,O)zirconium(IV) dimethylformamide disolvate |
title_short | Tetrakis(5,7-dimethylquinolin-8-olato-κ(2)
N,O)zirconium(IV) dimethylformamide disolvate |
title_sort | tetrakis(5,7-dimethylquinolin-8-olato-κ(2)
n,o)zirconium(iv) dimethylformamide disolvate |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3515106/ https://www.ncbi.nlm.nih.gov/pubmed/23284333 http://dx.doi.org/10.1107/S1600536812042092 |
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