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Bis(2,2′-bipyrimidine-κ(2) N (1),N (1′))palladium(II) bis­(tetra­fluoro­borate) acetonitrile monosolvate

The reaction of [Pd(MeCN)(4)](BF(4))(2) with 2,2′-bipyrimidine (bpm) in MeCN–CHCl(3) afforded the title compound, [Pd(C(8)H(6)N(4))(2)](BF(4))(2)·C(2)H(3)N. The asymmetric unit contains two half complexes, with the Pd(II) atoms both lying on a twofold axis. Each metal atom adopts a tetra­hedrally di...

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Detalles Bibliográficos
Autores principales: Duong, Adam, Wuest, James D., Maris, Thierry
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3515108/
https://www.ncbi.nlm.nih.gov/pubmed/23284335
http://dx.doi.org/10.1107/S1600536812041591
Descripción
Sumario:The reaction of [Pd(MeCN)(4)](BF(4))(2) with 2,2′-bipyrimidine (bpm) in MeCN–CHCl(3) afforded the title compound, [Pd(C(8)H(6)N(4))(2)](BF(4))(2)·C(2)H(3)N. The asymmetric unit contains two half complexes, with the Pd(II) atoms both lying on a twofold axis. Each metal atom adopts a tetra­hedrally distorted square-planar geometry. In the crystal, [Pd(bpm)(2)] dications are linked by C—H⋯N hydrogen bonds, forming chains parallel to the b axis. The chains are further linked by C—H⋯F and C—H⋯N inter­actions involving the tetra­fluoro­borate anions and acetonitrile mol­ecules. In this way, each chain interacts with six surrounding chains to generate the observed three-dimensional structure.