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Bis(2,2′-bipyrimidine-κ(2) N (1),N (1′))palladium(II) bis(tetrafluoroborate) acetonitrile monosolvate
The reaction of [Pd(MeCN)(4)](BF(4))(2) with 2,2′-bipyrimidine (bpm) in MeCN–CHCl(3) afforded the title compound, [Pd(C(8)H(6)N(4))(2)](BF(4))(2)·C(2)H(3)N. The asymmetric unit contains two half complexes, with the Pd(II) atoms both lying on a twofold axis. Each metal atom adopts a tetrahedrally di...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3515108/ https://www.ncbi.nlm.nih.gov/pubmed/23284335 http://dx.doi.org/10.1107/S1600536812041591 |
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author | Duong, Adam Wuest, James D. Maris, Thierry |
author_facet | Duong, Adam Wuest, James D. Maris, Thierry |
author_sort | Duong, Adam |
collection | PubMed |
description | The reaction of [Pd(MeCN)(4)](BF(4))(2) with 2,2′-bipyrimidine (bpm) in MeCN–CHCl(3) afforded the title compound, [Pd(C(8)H(6)N(4))(2)](BF(4))(2)·C(2)H(3)N. The asymmetric unit contains two half complexes, with the Pd(II) atoms both lying on a twofold axis. Each metal atom adopts a tetrahedrally distorted square-planar geometry. In the crystal, [Pd(bpm)(2)] dications are linked by C—H⋯N hydrogen bonds, forming chains parallel to the b axis. The chains are further linked by C—H⋯F and C—H⋯N interactions involving the tetrafluoroborate anions and acetonitrile molecules. In this way, each chain interacts with six surrounding chains to generate the observed three-dimensional structure. |
format | Online Article Text |
id | pubmed-3515108 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2012 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-35151082013-01-02 Bis(2,2′-bipyrimidine-κ(2) N (1),N (1′))palladium(II) bis(tetrafluoroborate) acetonitrile monosolvate Duong, Adam Wuest, James D. Maris, Thierry Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The reaction of [Pd(MeCN)(4)](BF(4))(2) with 2,2′-bipyrimidine (bpm) in MeCN–CHCl(3) afforded the title compound, [Pd(C(8)H(6)N(4))(2)](BF(4))(2)·C(2)H(3)N. The asymmetric unit contains two half complexes, with the Pd(II) atoms both lying on a twofold axis. Each metal atom adopts a tetrahedrally distorted square-planar geometry. In the crystal, [Pd(bpm)(2)] dications are linked by C—H⋯N hydrogen bonds, forming chains parallel to the b axis. The chains are further linked by C—H⋯F and C—H⋯N interactions involving the tetrafluoroborate anions and acetonitrile molecules. In this way, each chain interacts with six surrounding chains to generate the observed three-dimensional structure. International Union of Crystallography 2012-10-13 /pmc/articles/PMC3515108/ /pubmed/23284335 http://dx.doi.org/10.1107/S1600536812041591 Text en © Duong et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Duong, Adam Wuest, James D. Maris, Thierry Bis(2,2′-bipyrimidine-κ(2) N (1),N (1′))palladium(II) bis(tetrafluoroborate) acetonitrile monosolvate |
title | Bis(2,2′-bipyrimidine-κ(2)
N
(1),N
(1′))palladium(II) bis(tetrafluoroborate) acetonitrile monosolvate |
title_full | Bis(2,2′-bipyrimidine-κ(2)
N
(1),N
(1′))palladium(II) bis(tetrafluoroborate) acetonitrile monosolvate |
title_fullStr | Bis(2,2′-bipyrimidine-κ(2)
N
(1),N
(1′))palladium(II) bis(tetrafluoroborate) acetonitrile monosolvate |
title_full_unstemmed | Bis(2,2′-bipyrimidine-κ(2)
N
(1),N
(1′))palladium(II) bis(tetrafluoroborate) acetonitrile monosolvate |
title_short | Bis(2,2′-bipyrimidine-κ(2)
N
(1),N
(1′))palladium(II) bis(tetrafluoroborate) acetonitrile monosolvate |
title_sort | bis(2,2′-bipyrimidine-κ(2)
n
(1),n
(1′))palladium(ii) bis(tetrafluoroborate) acetonitrile monosolvate |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3515108/ https://www.ncbi.nlm.nih.gov/pubmed/23284335 http://dx.doi.org/10.1107/S1600536812041591 |
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