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Bis(2,2′-bipyrimidine-κ(2) N (1),N (1′))palladium(II) bis­(tetra­fluoro­borate) acetonitrile monosolvate

The reaction of [Pd(MeCN)(4)](BF(4))(2) with 2,2′-bipyrimidine (bpm) in MeCN–CHCl(3) afforded the title compound, [Pd(C(8)H(6)N(4))(2)](BF(4))(2)·C(2)H(3)N. The asymmetric unit contains two half complexes, with the Pd(II) atoms both lying on a twofold axis. Each metal atom adopts a tetra­hedrally di...

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Detalles Bibliográficos
Autores principales: Duong, Adam, Wuest, James D., Maris, Thierry
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3515108/
https://www.ncbi.nlm.nih.gov/pubmed/23284335
http://dx.doi.org/10.1107/S1600536812041591
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author Duong, Adam
Wuest, James D.
Maris, Thierry
author_facet Duong, Adam
Wuest, James D.
Maris, Thierry
author_sort Duong, Adam
collection PubMed
description The reaction of [Pd(MeCN)(4)](BF(4))(2) with 2,2′-bipyrimidine (bpm) in MeCN–CHCl(3) afforded the title compound, [Pd(C(8)H(6)N(4))(2)](BF(4))(2)·C(2)H(3)N. The asymmetric unit contains two half complexes, with the Pd(II) atoms both lying on a twofold axis. Each metal atom adopts a tetra­hedrally distorted square-planar geometry. In the crystal, [Pd(bpm)(2)] dications are linked by C—H⋯N hydrogen bonds, forming chains parallel to the b axis. The chains are further linked by C—H⋯F and C—H⋯N inter­actions involving the tetra­fluoro­borate anions and acetonitrile mol­ecules. In this way, each chain interacts with six surrounding chains to generate the observed three-dimensional structure.
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spelling pubmed-35151082013-01-02 Bis(2,2′-bipyrimidine-κ(2) N (1),N (1′))palladium(II) bis­(tetra­fluoro­borate) acetonitrile monosolvate Duong, Adam Wuest, James D. Maris, Thierry Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The reaction of [Pd(MeCN)(4)](BF(4))(2) with 2,2′-bipyrimidine (bpm) in MeCN–CHCl(3) afforded the title compound, [Pd(C(8)H(6)N(4))(2)](BF(4))(2)·C(2)H(3)N. The asymmetric unit contains two half complexes, with the Pd(II) atoms both lying on a twofold axis. Each metal atom adopts a tetra­hedrally distorted square-planar geometry. In the crystal, [Pd(bpm)(2)] dications are linked by C—H⋯N hydrogen bonds, forming chains parallel to the b axis. The chains are further linked by C—H⋯F and C—H⋯N inter­actions involving the tetra­fluoro­borate anions and acetonitrile mol­ecules. In this way, each chain interacts with six surrounding chains to generate the observed three-dimensional structure. International Union of Crystallography 2012-10-13 /pmc/articles/PMC3515108/ /pubmed/23284335 http://dx.doi.org/10.1107/S1600536812041591 Text en © Duong et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Duong, Adam
Wuest, James D.
Maris, Thierry
Bis(2,2′-bipyrimidine-κ(2) N (1),N (1′))palladium(II) bis­(tetra­fluoro­borate) acetonitrile monosolvate
title Bis(2,2′-bipyrimidine-κ(2) N (1),N (1′))palladium(II) bis­(tetra­fluoro­borate) acetonitrile monosolvate
title_full Bis(2,2′-bipyrimidine-κ(2) N (1),N (1′))palladium(II) bis­(tetra­fluoro­borate) acetonitrile monosolvate
title_fullStr Bis(2,2′-bipyrimidine-κ(2) N (1),N (1′))palladium(II) bis­(tetra­fluoro­borate) acetonitrile monosolvate
title_full_unstemmed Bis(2,2′-bipyrimidine-κ(2) N (1),N (1′))palladium(II) bis­(tetra­fluoro­borate) acetonitrile monosolvate
title_short Bis(2,2′-bipyrimidine-κ(2) N (1),N (1′))palladium(II) bis­(tetra­fluoro­borate) acetonitrile monosolvate
title_sort bis(2,2′-bipyrimidine-κ(2) n (1),n (1′))palladium(ii) bis­(tetra­fluoro­borate) acetonitrile monosolvate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3515108/
https://www.ncbi.nlm.nih.gov/pubmed/23284335
http://dx.doi.org/10.1107/S1600536812041591
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