Cargando…
Poly[aqua(μ(2)-pyrimidine-2-carboxylato-κ(4) O,N:O′,N′)(nitrato-κO)cadmium]
In the title polymer, [Cd(C(5)H(3)N(2)O(2))(NO(3))(H(2)O)](n), the Cd(II) atom is seven-coordinate in a distorted capped octahedral geometry by two N atoms of two different pyrimidine dicarboxylate (pmc) ligands, three O atoms from three separate pmc ligands, and two O atoms of disordered nitrate...
Autores principales: | , , |
---|---|
Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3515109/ https://www.ncbi.nlm.nih.gov/pubmed/23284336 http://dx.doi.org/10.1107/S1600536812041645 |
Sumario: | In the title polymer, [Cd(C(5)H(3)N(2)O(2))(NO(3))(H(2)O)](n), the Cd(II) atom is seven-coordinate in a distorted capped octahedral geometry by two N atoms of two different pyrimidine dicarboxylate (pmc) ligands, three O atoms from three separate pmc ligands, and two O atoms of disordered nitrate anions or water molecules. The Cd(II) atoms are bridged by the pmc ligands in a chelating/bridging bis-bidentate and chelating bidentate mode, forming sheets parallel to (20-1). The sheets are further linked into a three-dimensional supramolecular network via classical O—H⋯O hydrogen bonds involving the nitrate anions and coordinating water molecules. Intramolecular O—H⋯O hydrogen bonding is also observed. The non-coordinating nitrate O atoms are disordered over two sets of sites with occupancies of 0.57 (7) and 0.43 (7). |
---|