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Poly[aqua­(μ(2)-pyrimidine-2-carboxyl­ato-κ(4) O,N:O′,N′)(nitrato-κO)cadmium]

In the title polymer, [Cd(C(5)H(3)N(2)O(2))(NO(3))(H(2)O)](n), the Cd(II) atom is seven-coordinate in a distorted capped octa­hedral geometry by two N atoms of two different pyrimidine dicarboxyl­ate (pmc) ligands, three O atoms from three separate pmc ligands, and two O atoms of disordered nitrate...

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Detalles Bibliográficos
Autores principales: In-noi, Orrasa, Chainok, Kittipnog, Harding, David J.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3515109/
https://www.ncbi.nlm.nih.gov/pubmed/23284336
http://dx.doi.org/10.1107/S1600536812041645
Descripción
Sumario:In the title polymer, [Cd(C(5)H(3)N(2)O(2))(NO(3))(H(2)O)](n), the Cd(II) atom is seven-coordinate in a distorted capped octa­hedral geometry by two N atoms of two different pyrimidine dicarboxyl­ate (pmc) ligands, three O atoms from three separate pmc ligands, and two O atoms of disordered nitrate anions or water mol­ecules. The Cd(II) atoms are bridged by the pmc ligands in a chelating/bridging bis-bidentate and chelating bidentate mode, forming sheets parallel to (20-1). The sheets are further linked into a three-dimensional supra­molecular network via classical O—H⋯O hydrogen bonds involving the nitrate anions and coordinating water mol­ecules. Intra­molecular O—H⋯O hydrogen bonding is also observed. The non-coordinating nitrate O atoms are disordered over two sets of sites with occupancies of 0.57 (7) and 0.43 (7).