trans-Dichloridobis(4-nitro­aniline-κN (1))palladium(II)

In the title compound, [PdCl(2)(C(6)H(6)N(2)O(2))(2)], the Pd(II) atom is coordinated in a distorted square-planar geometry by two N atoms from two 4-nitro­aniline ligands and two Cl atoms in a trans arrangement. Inter­molecular N—H⋯Cl hydrogen bonds involving the amino groups and chloride anions le...

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Detalles Bibliográficos
Autor principal: Feng, Tian-Jun
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3515110/
https://www.ncbi.nlm.nih.gov/pubmed/23284337
http://dx.doi.org/10.1107/S1600536812042134
Descripción
Sumario:In the title compound, [PdCl(2)(C(6)H(6)N(2)O(2))(2)], the Pd(II) atom is coordinated in a distorted square-planar geometry by two N atoms from two 4-nitro­aniline ligands and two Cl atoms in a trans arrangement. Inter­molecular N—H⋯Cl hydrogen bonds involving the amino groups and chloride anions lead to a chain along [100]. These chains are further self-assembled into a three-dimensional network through N—H⋯O and N—H⋯Cl hydrogen bonds.

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