trans-Dichloridobis(4-nitro­aniline-κN (1))palladium(II)

In the title compound, [PdCl(2)(C(6)H(6)N(2)O(2))(2)], the Pd(II) atom is coordinated in a distorted square-planar geometry by two N atoms from two 4-nitro­aniline ligands and two Cl atoms in a trans arrangement. Inter­molecular N—H⋯Cl hydrogen bonds involving the amino groups and chloride anions le...

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Detalles Bibliográficos
Autor principal: Feng, Tian-Jun
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3515110/
https://www.ncbi.nlm.nih.gov/pubmed/23284337
http://dx.doi.org/10.1107/S1600536812042134
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author Feng, Tian-Jun
author_facet Feng, Tian-Jun
author_sort Feng, Tian-Jun
collection PubMed
description In the title compound, [PdCl(2)(C(6)H(6)N(2)O(2))(2)], the Pd(II) atom is coordinated in a distorted square-planar geometry by two N atoms from two 4-nitro­aniline ligands and two Cl atoms in a trans arrangement. Inter­molecular N—H⋯Cl hydrogen bonds involving the amino groups and chloride anions lead to a chain along [100]. These chains are further self-assembled into a three-dimensional network through N—H⋯O and N—H⋯Cl hydrogen bonds.
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spelling pubmed-35151102013-01-02 trans-Dichloridobis(4-nitro­aniline-κN (1))palladium(II) Feng, Tian-Jun Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [PdCl(2)(C(6)H(6)N(2)O(2))(2)], the Pd(II) atom is coordinated in a distorted square-planar geometry by two N atoms from two 4-nitro­aniline ligands and two Cl atoms in a trans arrangement. Inter­molecular N—H⋯Cl hydrogen bonds involving the amino groups and chloride anions lead to a chain along [100]. These chains are further self-assembled into a three-dimensional network through N—H⋯O and N—H⋯Cl hydrogen bonds. International Union of Crystallography 2012-10-13 /pmc/articles/PMC3515110/ /pubmed/23284337 http://dx.doi.org/10.1107/S1600536812042134 Text en © Tian-Jun Feng 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Feng, Tian-Jun
trans-Dichloridobis(4-nitro­aniline-κN (1))palladium(II)
title trans-Dichloridobis(4-nitro­aniline-κN (1))palladium(II)
title_full trans-Dichloridobis(4-nitro­aniline-κN (1))palladium(II)
title_fullStr trans-Dichloridobis(4-nitro­aniline-κN (1))palladium(II)
title_full_unstemmed trans-Dichloridobis(4-nitro­aniline-κN (1))palladium(II)
title_short trans-Dichloridobis(4-nitro­aniline-κN (1))palladium(II)
title_sort trans-dichloridobis(4-nitro­aniline-κn (1))palladium(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3515110/
https://www.ncbi.nlm.nih.gov/pubmed/23284337
http://dx.doi.org/10.1107/S1600536812042134
work_keys_str_mv AT fengtianjun transdichloridobis4nitroanilinekn1palladiumii

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