(Acetato-κO)(acetato-κO,O′)bis­(1,3-diazinane-2-thione-κS)cadmium(II)

In the title complex, [Cd(CH(3)COO)(2)(C(4)H(8)N(2)S)(2)], the Cd(II) cation is coordinated by three acetate O atoms and two S atoms of Diaz [Diaz = 1,3-diazinane-2-thione = 3,4,5,6-tetra­hydro­pyrimidine-2(1H)-thione]. The Cd(II) coordination is augmented by one considerably longer Cd—O bond of 2.7...

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Autores principales: Mahmood, Rashid, Ghulam Hussain, Saima, Fettouhi, Mohammed, Isab, Anvarhusein A., Ahmad, Saeed
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3515111/
https://www.ncbi.nlm.nih.gov/pubmed/23284338
http://dx.doi.org/10.1107/S1600536812041852
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author Mahmood, Rashid
Ghulam Hussain, Saima
Fettouhi, Mohammed
Isab, Anvarhusein A.
Ahmad, Saeed
author_facet Mahmood, Rashid
Ghulam Hussain, Saima
Fettouhi, Mohammed
Isab, Anvarhusein A.
Ahmad, Saeed
author_sort Mahmood, Rashid
collection PubMed
description In the title complex, [Cd(CH(3)COO)(2)(C(4)H(8)N(2)S)(2)], the Cd(II) cation is coordinated by three acetate O atoms and two S atoms of Diaz [Diaz = 1,3-diazinane-2-thione = 3,4,5,6-tetra­hydro­pyrimidine-2(1H)-thione]. The Cd(II) coordination is augmented by one considerably longer Cd—O bond of 2.782 (3) Å to a carboxyl­ate O atom. The resulting coordination polyhedron around the Cd(II) cations can be described as a highly distorted octa­hedron. The Diaz ligand and the acetate anions are linked by N—H⋯O hydrogen-bonding inter­actions.
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spelling pubmed-35151112013-01-02 (Acetato-κO)(acetato-κO,O′)bis­(1,3-diazinane-2-thione-κS)cadmium(II) Mahmood, Rashid Ghulam Hussain, Saima Fettouhi, Mohammed Isab, Anvarhusein A. Ahmad, Saeed Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [Cd(CH(3)COO)(2)(C(4)H(8)N(2)S)(2)], the Cd(II) cation is coordinated by three acetate O atoms and two S atoms of Diaz [Diaz = 1,3-diazinane-2-thione = 3,4,5,6-tetra­hydro­pyrimidine-2(1H)-thione]. The Cd(II) coordination is augmented by one considerably longer Cd—O bond of 2.782 (3) Å to a carboxyl­ate O atom. The resulting coordination polyhedron around the Cd(II) cations can be described as a highly distorted octa­hedron. The Diaz ligand and the acetate anions are linked by N—H⋯O hydrogen-bonding inter­actions. International Union of Crystallography 2012-10-13 /pmc/articles/PMC3515111/ /pubmed/23284338 http://dx.doi.org/10.1107/S1600536812041852 Text en © Mahmood et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Mahmood, Rashid
Ghulam Hussain, Saima
Fettouhi, Mohammed
Isab, Anvarhusein A.
Ahmad, Saeed
(Acetato-κO)(acetato-κO,O′)bis­(1,3-diazinane-2-thione-κS)cadmium(II)
title (Acetato-κO)(acetato-κO,O′)bis­(1,3-diazinane-2-thione-κS)cadmium(II)
title_full (Acetato-κO)(acetato-κO,O′)bis­(1,3-diazinane-2-thione-κS)cadmium(II)
title_fullStr (Acetato-κO)(acetato-κO,O′)bis­(1,3-diazinane-2-thione-κS)cadmium(II)
title_full_unstemmed (Acetato-κO)(acetato-κO,O′)bis­(1,3-diazinane-2-thione-κS)cadmium(II)
title_short (Acetato-κO)(acetato-κO,O′)bis­(1,3-diazinane-2-thione-κS)cadmium(II)
title_sort (acetato-κo)(acetato-κo,o′)bis­(1,3-diazinane-2-thione-κs)cadmium(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3515111/
https://www.ncbi.nlm.nih.gov/pubmed/23284338
http://dx.doi.org/10.1107/S1600536812041852
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