Bis(diphenyl-p-tolyl­phosphane-κP)(2-hy­droxy-3,5,7-bromo­cyclo­hepta-2,4,6-trienonato-κ(2) O,O′)copper(I)

The Cu(I) atom in the title compund, [Cu(C(7)H(2)Br(3)O(2))(C(19)H(17)P)(2)], is located on a twofold rotation axis; the 3,5,7-tribromo­tropolonate anion coordinates as a bidentate ligand with a bite angle of 76.42 (9)°. An intra­molecular C—H⋯O inter­action occurs. Within the crystal, extensive wea...

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Detalles Bibliográficos
Autores principales: Barnard, Nicola I., Hill, Tania N.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3515112/
https://www.ncbi.nlm.nih.gov/pubmed/23284339
http://dx.doi.org/10.1107/S1600536812042286
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author Barnard, Nicola I.
Hill, Tania N.
author_facet Barnard, Nicola I.
Hill, Tania N.
author_sort Barnard, Nicola I.
collection PubMed
description The Cu(I) atom in the title compund, [Cu(C(7)H(2)Br(3)O(2))(C(19)H(17)P)(2)], is located on a twofold rotation axis; the 3,5,7-tribromo­tropolonate anion coordinates as a bidentate ligand with a bite angle of 76.42 (9)°. An intra­molecular C—H⋯O inter­action occurs. Within the crystal, extensive weak C—H⋯π inter­actions contribute to the herringbone pattern observed in the packing of the mol­ecules.
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spelling pubmed-35151122013-01-02 Bis(diphenyl-p-tolyl­phosphane-κP)(2-hy­droxy-3,5,7-bromo­cyclo­hepta-2,4,6-trienonato-κ(2) O,O′)copper(I) Barnard, Nicola I. Hill, Tania N. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The Cu(I) atom in the title compund, [Cu(C(7)H(2)Br(3)O(2))(C(19)H(17)P)(2)], is located on a twofold rotation axis; the 3,5,7-tribromo­tropolonate anion coordinates as a bidentate ligand with a bite angle of 76.42 (9)°. An intra­molecular C—H⋯O inter­action occurs. Within the crystal, extensive weak C—H⋯π inter­actions contribute to the herringbone pattern observed in the packing of the mol­ecules. International Union of Crystallography 2012-10-13 /pmc/articles/PMC3515112/ /pubmed/23284339 http://dx.doi.org/10.1107/S1600536812042286 Text en © Barnard and Hill 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Barnard, Nicola I.
Hill, Tania N.
Bis(diphenyl-p-tolyl­phosphane-κP)(2-hy­droxy-3,5,7-bromo­cyclo­hepta-2,4,6-trienonato-κ(2) O,O′)copper(I)
title Bis(diphenyl-p-tolyl­phosphane-κP)(2-hy­droxy-3,5,7-bromo­cyclo­hepta-2,4,6-trienonato-κ(2) O,O′)copper(I)
title_full Bis(diphenyl-p-tolyl­phosphane-κP)(2-hy­droxy-3,5,7-bromo­cyclo­hepta-2,4,6-trienonato-κ(2) O,O′)copper(I)
title_fullStr Bis(diphenyl-p-tolyl­phosphane-κP)(2-hy­droxy-3,5,7-bromo­cyclo­hepta-2,4,6-trienonato-κ(2) O,O′)copper(I)
title_full_unstemmed Bis(diphenyl-p-tolyl­phosphane-κP)(2-hy­droxy-3,5,7-bromo­cyclo­hepta-2,4,6-trienonato-κ(2) O,O′)copper(I)
title_short Bis(diphenyl-p-tolyl­phosphane-κP)(2-hy­droxy-3,5,7-bromo­cyclo­hepta-2,4,6-trienonato-κ(2) O,O′)copper(I)
title_sort bis(diphenyl-p-tolyl­phosphane-κp)(2-hy­droxy-3,5,7-bromo­cyclo­hepta-2,4,6-trienonato-κ(2) o,o′)copper(i)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3515112/
https://www.ncbi.nlm.nih.gov/pubmed/23284339
http://dx.doi.org/10.1107/S1600536812042286
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