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Bis[μ-(3-acetyl-2-hy­droxy-6-methyl-4H-pyran-4-one-κ(3) O:O′,O′′)]diaqua­tetra­kis­(pyridine-κN)dicopper(II) diperchlorate

In the centrosymmetric binuclear cation of the title compound, [Cu(C(8)H(7)O(4))(H(2)O)(C(5)H(5)N)(2)](2)(ClO(4))(2), the Cu(II) atoms are bridged by a pair of two dehydro­acetate anions in a bis-/monodentate mode. The distorted octa­hedral N(2)O(4) coordination sphere of the metal cation is complet...

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Autores principales: Ourari, Ali, Derafa, Wassila, Bouacida, Sofiane, Aggoun, Djouhra, Daran, Jean-Claude
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3515113/
https://www.ncbi.nlm.nih.gov/pubmed/23284340
http://dx.doi.org/10.1107/S1600536812041608
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author Ourari, Ali
Derafa, Wassila
Bouacida, Sofiane
Aggoun, Djouhra
Daran, Jean-Claude
author_facet Ourari, Ali
Derafa, Wassila
Bouacida, Sofiane
Aggoun, Djouhra
Daran, Jean-Claude
author_sort Ourari, Ali
collection PubMed
description In the centrosymmetric binuclear cation of the title compound, [Cu(C(8)H(7)O(4))(H(2)O)(C(5)H(5)N)(2)](2)(ClO(4))(2), the Cu(II) atoms are bridged by a pair of two dehydro­acetate anions in a bis-/monodentate mode. The distorted octa­hedral N(2)O(4) coordination sphere of the metal cation is completed by two pyridine N atoms and one O atom of a water mol­ecule. The complex cations and the perchlorate counter anions are arranged in layers parallel to (100). O—H⋯O hydrogen bonds between the coordinating water mol­ecules and the perchlorate anions constitute ribbons parallel to [10-1]. C—H⋯O hydrogen bonds are also observed.
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spelling pubmed-35151132013-01-02 Bis[μ-(3-acetyl-2-hy­droxy-6-methyl-4H-pyran-4-one-κ(3) O:O′,O′′)]diaqua­tetra­kis­(pyridine-κN)dicopper(II) diperchlorate Ourari, Ali Derafa, Wassila Bouacida, Sofiane Aggoun, Djouhra Daran, Jean-Claude Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the centrosymmetric binuclear cation of the title compound, [Cu(C(8)H(7)O(4))(H(2)O)(C(5)H(5)N)(2)](2)(ClO(4))(2), the Cu(II) atoms are bridged by a pair of two dehydro­acetate anions in a bis-/monodentate mode. The distorted octa­hedral N(2)O(4) coordination sphere of the metal cation is completed by two pyridine N atoms and one O atom of a water mol­ecule. The complex cations and the perchlorate counter anions are arranged in layers parallel to (100). O—H⋯O hydrogen bonds between the coordinating water mol­ecules and the perchlorate anions constitute ribbons parallel to [10-1]. C—H⋯O hydrogen bonds are also observed. International Union of Crystallography 2012-10-13 /pmc/articles/PMC3515113/ /pubmed/23284340 http://dx.doi.org/10.1107/S1600536812041608 Text en © Ourari et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Ourari, Ali
Derafa, Wassila
Bouacida, Sofiane
Aggoun, Djouhra
Daran, Jean-Claude
Bis[μ-(3-acetyl-2-hy­droxy-6-methyl-4H-pyran-4-one-κ(3) O:O′,O′′)]diaqua­tetra­kis­(pyridine-κN)dicopper(II) diperchlorate
title Bis[μ-(3-acetyl-2-hy­droxy-6-methyl-4H-pyran-4-one-κ(3) O:O′,O′′)]diaqua­tetra­kis­(pyridine-κN)dicopper(II) diperchlorate
title_full Bis[μ-(3-acetyl-2-hy­droxy-6-methyl-4H-pyran-4-one-κ(3) O:O′,O′′)]diaqua­tetra­kis­(pyridine-κN)dicopper(II) diperchlorate
title_fullStr Bis[μ-(3-acetyl-2-hy­droxy-6-methyl-4H-pyran-4-one-κ(3) O:O′,O′′)]diaqua­tetra­kis­(pyridine-κN)dicopper(II) diperchlorate
title_full_unstemmed Bis[μ-(3-acetyl-2-hy­droxy-6-methyl-4H-pyran-4-one-κ(3) O:O′,O′′)]diaqua­tetra­kis­(pyridine-κN)dicopper(II) diperchlorate
title_short Bis[μ-(3-acetyl-2-hy­droxy-6-methyl-4H-pyran-4-one-κ(3) O:O′,O′′)]diaqua­tetra­kis­(pyridine-κN)dicopper(II) diperchlorate
title_sort bis[μ-(3-acetyl-2-hy­droxy-6-methyl-4h-pyran-4-one-κ(3) o:o′,o′′)]diaqua­tetra­kis­(pyridine-κn)dicopper(ii) diperchlorate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3515113/
https://www.ncbi.nlm.nih.gov/pubmed/23284340
http://dx.doi.org/10.1107/S1600536812041608
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