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Bis[μ-(3-acetyl-2-hydroxy-6-methyl-4H-pyran-4-one-κ(3) O:O′,O′′)]diaquatetrakis(pyridine-κN)dicopper(II) diperchlorate
In the centrosymmetric binuclear cation of the title compound, [Cu(C(8)H(7)O(4))(H(2)O)(C(5)H(5)N)(2)](2)(ClO(4))(2), the Cu(II) atoms are bridged by a pair of two dehydroacetate anions in a bis-/monodentate mode. The distorted octahedral N(2)O(4) coordination sphere of the metal cation is complet...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3515113/ https://www.ncbi.nlm.nih.gov/pubmed/23284340 http://dx.doi.org/10.1107/S1600536812041608 |
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author | Ourari, Ali Derafa, Wassila Bouacida, Sofiane Aggoun, Djouhra Daran, Jean-Claude |
author_facet | Ourari, Ali Derafa, Wassila Bouacida, Sofiane Aggoun, Djouhra Daran, Jean-Claude |
author_sort | Ourari, Ali |
collection | PubMed |
description | In the centrosymmetric binuclear cation of the title compound, [Cu(C(8)H(7)O(4))(H(2)O)(C(5)H(5)N)(2)](2)(ClO(4))(2), the Cu(II) atoms are bridged by a pair of two dehydroacetate anions in a bis-/monodentate mode. The distorted octahedral N(2)O(4) coordination sphere of the metal cation is completed by two pyridine N atoms and one O atom of a water molecule. The complex cations and the perchlorate counter anions are arranged in layers parallel to (100). O—H⋯O hydrogen bonds between the coordinating water molecules and the perchlorate anions constitute ribbons parallel to [10-1]. C—H⋯O hydrogen bonds are also observed. |
format | Online Article Text |
id | pubmed-3515113 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2012 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-35151132013-01-02 Bis[μ-(3-acetyl-2-hydroxy-6-methyl-4H-pyran-4-one-κ(3) O:O′,O′′)]diaquatetrakis(pyridine-κN)dicopper(II) diperchlorate Ourari, Ali Derafa, Wassila Bouacida, Sofiane Aggoun, Djouhra Daran, Jean-Claude Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the centrosymmetric binuclear cation of the title compound, [Cu(C(8)H(7)O(4))(H(2)O)(C(5)H(5)N)(2)](2)(ClO(4))(2), the Cu(II) atoms are bridged by a pair of two dehydroacetate anions in a bis-/monodentate mode. The distorted octahedral N(2)O(4) coordination sphere of the metal cation is completed by two pyridine N atoms and one O atom of a water molecule. The complex cations and the perchlorate counter anions are arranged in layers parallel to (100). O—H⋯O hydrogen bonds between the coordinating water molecules and the perchlorate anions constitute ribbons parallel to [10-1]. C—H⋯O hydrogen bonds are also observed. International Union of Crystallography 2012-10-13 /pmc/articles/PMC3515113/ /pubmed/23284340 http://dx.doi.org/10.1107/S1600536812041608 Text en © Ourari et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Ourari, Ali Derafa, Wassila Bouacida, Sofiane Aggoun, Djouhra Daran, Jean-Claude Bis[μ-(3-acetyl-2-hydroxy-6-methyl-4H-pyran-4-one-κ(3) O:O′,O′′)]diaquatetrakis(pyridine-κN)dicopper(II) diperchlorate |
title | Bis[μ-(3-acetyl-2-hydroxy-6-methyl-4H-pyran-4-one-κ(3)
O:O′,O′′)]diaquatetrakis(pyridine-κN)dicopper(II) diperchlorate |
title_full | Bis[μ-(3-acetyl-2-hydroxy-6-methyl-4H-pyran-4-one-κ(3)
O:O′,O′′)]diaquatetrakis(pyridine-κN)dicopper(II) diperchlorate |
title_fullStr | Bis[μ-(3-acetyl-2-hydroxy-6-methyl-4H-pyran-4-one-κ(3)
O:O′,O′′)]diaquatetrakis(pyridine-κN)dicopper(II) diperchlorate |
title_full_unstemmed | Bis[μ-(3-acetyl-2-hydroxy-6-methyl-4H-pyran-4-one-κ(3)
O:O′,O′′)]diaquatetrakis(pyridine-κN)dicopper(II) diperchlorate |
title_short | Bis[μ-(3-acetyl-2-hydroxy-6-methyl-4H-pyran-4-one-κ(3)
O:O′,O′′)]diaquatetrakis(pyridine-κN)dicopper(II) diperchlorate |
title_sort | bis[μ-(3-acetyl-2-hydroxy-6-methyl-4h-pyran-4-one-κ(3)
o:o′,o′′)]diaquatetrakis(pyridine-κn)dicopper(ii) diperchlorate |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3515113/ https://www.ncbi.nlm.nih.gov/pubmed/23284340 http://dx.doi.org/10.1107/S1600536812041608 |
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