Potassium N-bromo-2-nitro­benzene­sulfonamidate monohydrate

In the title compound, K(+)·C(6)H(4)BrN(2)O(4)S(−)·H(2)O, the K(+) ion is hepta-coordinated by two O atoms from two different water mol­ecules, three sulfonyl O atoms from three N-bromo-2-nitro-benzene­sulfonamidate anions and two nitro O atoms from two N-bromo-2-nitro-benzene­sulfonamidate anions....

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Detalles Bibliográficos
Autores principales: Gowda, B. Thimme, Foro, Sabine, Spandana, H. S.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3515114/
https://www.ncbi.nlm.nih.gov/pubmed/23284341
http://dx.doi.org/10.1107/S1600536812042080
Descripción
Sumario:In the title compound, K(+)·C(6)H(4)BrN(2)O(4)S(−)·H(2)O, the K(+) ion is hepta-coordinated by two O atoms from two different water mol­ecules, three sulfonyl O atoms from three N-bromo-2-nitro-benzene­sulfonamidate anions and two nitro O atoms from two N-bromo-2-nitro-benzene­sulfonamidate anions. The S—N distance of 1.576 (4) Å is consistent with an S=N double bond. The crystal structure is stabilized by inter­molecular O—H⋯N and O—H⋯Br hydrogen bonds which link the molecules into polymeric layers running parallel to the bc plane.

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