Potassium N-bromo-2-nitro­benzene­sulfonamidate monohydrate

In the title compound, K(+)·C(6)H(4)BrN(2)O(4)S(−)·H(2)O, the K(+) ion is hepta-coordinated by two O atoms from two different water mol­ecules, three sulfonyl O atoms from three N-bromo-2-nitro-benzene­sulfonamidate anions and two nitro O atoms from two N-bromo-2-nitro-benzene­sulfonamidate anions....

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Detalles Bibliográficos
Autores principales: Gowda, B. Thimme, Foro, Sabine, Spandana, H. S.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3515114/
https://www.ncbi.nlm.nih.gov/pubmed/23284341
http://dx.doi.org/10.1107/S1600536812042080
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author Gowda, B. Thimme
Foro, Sabine
Spandana, H. S.
author_facet Gowda, B. Thimme
Foro, Sabine
Spandana, H. S.
author_sort Gowda, B. Thimme
collection PubMed
description In the title compound, K(+)·C(6)H(4)BrN(2)O(4)S(−)·H(2)O, the K(+) ion is hepta-coordinated by two O atoms from two different water mol­ecules, three sulfonyl O atoms from three N-bromo-2-nitro-benzene­sulfonamidate anions and two nitro O atoms from two N-bromo-2-nitro-benzene­sulfonamidate anions. The S—N distance of 1.576 (4) Å is consistent with an S=N double bond. The crystal structure is stabilized by inter­molecular O—H⋯N and O—H⋯Br hydrogen bonds which link the molecules into polymeric layers running parallel to the bc plane.
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spelling pubmed-35151142013-01-02 Potassium N-bromo-2-nitro­benzene­sulfonamidate monohydrate Gowda, B. Thimme Foro, Sabine Spandana, H. S. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, K(+)·C(6)H(4)BrN(2)O(4)S(−)·H(2)O, the K(+) ion is hepta-coordinated by two O atoms from two different water mol­ecules, three sulfonyl O atoms from three N-bromo-2-nitro-benzene­sulfonamidate anions and two nitro O atoms from two N-bromo-2-nitro-benzene­sulfonamidate anions. The S—N distance of 1.576 (4) Å is consistent with an S=N double bond. The crystal structure is stabilized by inter­molecular O—H⋯N and O—H⋯Br hydrogen bonds which link the molecules into polymeric layers running parallel to the bc plane. International Union of Crystallography 2012-10-13 /pmc/articles/PMC3515114/ /pubmed/23284341 http://dx.doi.org/10.1107/S1600536812042080 Text en © Gowda et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Gowda, B. Thimme
Foro, Sabine
Spandana, H. S.
Potassium N-bromo-2-nitro­benzene­sulfonamidate monohydrate
title Potassium N-bromo-2-nitro­benzene­sulfonamidate monohydrate
title_full Potassium N-bromo-2-nitro­benzene­sulfonamidate monohydrate
title_fullStr Potassium N-bromo-2-nitro­benzene­sulfonamidate monohydrate
title_full_unstemmed Potassium N-bromo-2-nitro­benzene­sulfonamidate monohydrate
title_short Potassium N-bromo-2-nitro­benzene­sulfonamidate monohydrate
title_sort potassium n-bromo-2-nitro­benzene­sulfonamidate monohydrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3515114/
https://www.ncbi.nlm.nih.gov/pubmed/23284341
http://dx.doi.org/10.1107/S1600536812042080
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