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(Ammine)(carbonyl)[hydridotris(pyrazol-1-yl-κN (2))borato](triphenylphosphine-κP)ruthenium(II) chloride dichloromethane disolvate
In the title compound, [Ru(CO)(NH(3))(C(9)H(10)BN(6))(C(18)H(15)P)]Cl·2CH(2)Cl(2), the coordination environment around the Ru(II) atom is distorted octahedral. One of the Ru—N(Tp) [Tp = hydridotris(pyrazol-1-yl)borate] bond lengths is slightly longer than the other two as a result of the influence...
| Autores principales: | , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2012
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3515116/ https://www.ncbi.nlm.nih.gov/pubmed/23284343 http://dx.doi.org/10.1107/S160053681204247X |
| _version_ | 1782252114078072832 |
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| author | Hu, Ting-Chuan Ye, Jun-Xlan He, Sheng-Ting Chiang, Guan-Ru Lo, Yih-Hsing |
| author_facet | Hu, Ting-Chuan Ye, Jun-Xlan He, Sheng-Ting Chiang, Guan-Ru Lo, Yih-Hsing |
| author_sort | Hu, Ting-Chuan |
| collection | PubMed |
| description | In the title compound, [Ru(CO)(NH(3))(C(9)H(10)BN(6))(C(18)H(15)P)]Cl·2CH(2)Cl(2), the coordination environment around the Ru(II) atom is distorted octahedral. One of the Ru—N(Tp) [Tp = hydridotris(pyrazol-1-yl)borate] bond lengths is slightly longer than the other two as a result of the influence of the trans CO ligand. In the crystal, N—H⋯Cl hydrogen bonds link the complex cations and Cl(−) anions. π–π interactions between the pyrazole rings [centroid–centroid distance = 3.764 (3) Å] are also present. |
| format | Online Article Text |
| id | pubmed-3515116 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2012 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-35151162013-01-02 (Ammine)(carbonyl)[hydridotris(pyrazol-1-yl-κN (2))borato](triphenylphosphine-κP)ruthenium(II) chloride dichloromethane disolvate Hu, Ting-Chuan Ye, Jun-Xlan He, Sheng-Ting Chiang, Guan-Ru Lo, Yih-Hsing Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Ru(CO)(NH(3))(C(9)H(10)BN(6))(C(18)H(15)P)]Cl·2CH(2)Cl(2), the coordination environment around the Ru(II) atom is distorted octahedral. One of the Ru—N(Tp) [Tp = hydridotris(pyrazol-1-yl)borate] bond lengths is slightly longer than the other two as a result of the influence of the trans CO ligand. In the crystal, N—H⋯Cl hydrogen bonds link the complex cations and Cl(−) anions. π–π interactions between the pyrazole rings [centroid–centroid distance = 3.764 (3) Å] are also present. International Union of Crystallography 2012-10-13 /pmc/articles/PMC3515116/ /pubmed/23284343 http://dx.doi.org/10.1107/S160053681204247X Text en © Hu et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Hu, Ting-Chuan Ye, Jun-Xlan He, Sheng-Ting Chiang, Guan-Ru Lo, Yih-Hsing (Ammine)(carbonyl)[hydridotris(pyrazol-1-yl-κN (2))borato](triphenylphosphine-κP)ruthenium(II) chloride dichloromethane disolvate |
| title | (Ammine)(carbonyl)[hydridotris(pyrazol-1-yl-κN
(2))borato](triphenylphosphine-κP)ruthenium(II) chloride dichloromethane disolvate |
| title_full | (Ammine)(carbonyl)[hydridotris(pyrazol-1-yl-κN
(2))borato](triphenylphosphine-κP)ruthenium(II) chloride dichloromethane disolvate |
| title_fullStr | (Ammine)(carbonyl)[hydridotris(pyrazol-1-yl-κN
(2))borato](triphenylphosphine-κP)ruthenium(II) chloride dichloromethane disolvate |
| title_full_unstemmed | (Ammine)(carbonyl)[hydridotris(pyrazol-1-yl-κN
(2))borato](triphenylphosphine-κP)ruthenium(II) chloride dichloromethane disolvate |
| title_short | (Ammine)(carbonyl)[hydridotris(pyrazol-1-yl-κN
(2))borato](triphenylphosphine-κP)ruthenium(II) chloride dichloromethane disolvate |
| title_sort | (ammine)(carbonyl)[hydridotris(pyrazol-1-yl-κn
(2))borato](triphenylphosphine-κp)ruthenium(ii) chloride dichloromethane disolvate |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3515116/ https://www.ncbi.nlm.nih.gov/pubmed/23284343 http://dx.doi.org/10.1107/S160053681204247X |
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