Dibromido(6,6′-dimethyl-2,2′-bipyridine-κ(2) N,N′)cobalt(II)

In the title compound, [CoBr(2)(C(12)H(12)N(2))], the Co(II) atom is four-coordinated in a distorted tetra­hedral geometry by two N atoms from a 6,6′-dimethyl-2,2′-bipyridine ligand and by two terminal Br atoms. Inter­molecular C—H⋯Br hydrogen bonds and π–π stacking between the pyridine rings in the...

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Autores principales: Shirvan, Sadif A., Haydari Dezfuli, Sara, Khazali, Fereydoon, Aghajeri, Manouchehr, Borsalani, Ali
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3515117/
https://www.ncbi.nlm.nih.gov/pubmed/23284344
http://dx.doi.org/10.1107/S1600536812041980
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author Shirvan, Sadif A.
Haydari Dezfuli, Sara
Khazali, Fereydoon
Aghajeri, Manouchehr
Borsalani, Ali
author_facet Shirvan, Sadif A.
Haydari Dezfuli, Sara
Khazali, Fereydoon
Aghajeri, Manouchehr
Borsalani, Ali
author_sort Shirvan, Sadif A.
collection PubMed
description In the title compound, [CoBr(2)(C(12)H(12)N(2))], the Co(II) atom is four-coordinated in a distorted tetra­hedral geometry by two N atoms from a 6,6′-dimethyl-2,2′-bipyridine ligand and by two terminal Br atoms. Inter­molecular C—H⋯Br hydrogen bonds and π–π stacking between the pyridine rings in the bc plane [centroid–centroid distance = 3.725 (3) Å] are present in the crystal structure.
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spelling pubmed-35151172013-01-02 Dibromido(6,6′-dimethyl-2,2′-bipyridine-κ(2) N,N′)cobalt(II) Shirvan, Sadif A. Haydari Dezfuli, Sara Khazali, Fereydoon Aghajeri, Manouchehr Borsalani, Ali Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [CoBr(2)(C(12)H(12)N(2))], the Co(II) atom is four-coordinated in a distorted tetra­hedral geometry by two N atoms from a 6,6′-dimethyl-2,2′-bipyridine ligand and by two terminal Br atoms. Inter­molecular C—H⋯Br hydrogen bonds and π–π stacking between the pyridine rings in the bc plane [centroid–centroid distance = 3.725 (3) Å] are present in the crystal structure. International Union of Crystallography 2012-10-13 /pmc/articles/PMC3515117/ /pubmed/23284344 http://dx.doi.org/10.1107/S1600536812041980 Text en © Shirvan et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Shirvan, Sadif A.
Haydari Dezfuli, Sara
Khazali, Fereydoon
Aghajeri, Manouchehr
Borsalani, Ali
Dibromido(6,6′-dimethyl-2,2′-bipyridine-κ(2) N,N′)cobalt(II)
title Dibromido(6,6′-dimethyl-2,2′-bipyridine-κ(2) N,N′)cobalt(II)
title_full Dibromido(6,6′-dimethyl-2,2′-bipyridine-κ(2) N,N′)cobalt(II)
title_fullStr Dibromido(6,6′-dimethyl-2,2′-bipyridine-κ(2) N,N′)cobalt(II)
title_full_unstemmed Dibromido(6,6′-dimethyl-2,2′-bipyridine-κ(2) N,N′)cobalt(II)
title_short Dibromido(6,6′-dimethyl-2,2′-bipyridine-κ(2) N,N′)cobalt(II)
title_sort dibromido(6,6′-dimethyl-2,2′-bipyridine-κ(2) n,n′)cobalt(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3515117/
https://www.ncbi.nlm.nih.gov/pubmed/23284344
http://dx.doi.org/10.1107/S1600536812041980
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