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Poly[di-μ(3)-hy­droxy[μ(4)-5-(4-carb­oxy­phen­yl)pyridine-2-carboxyl­ato-κ(5) N,O (2):O (2′):O (4):O (4′)]dicadmium]

The asymmetric unit of the title polymeric complex, [Cd(2)(C(13)H(7)NO(4))(OH)(2)](n), consists of two independent Cd(II) atoms, one 5-(4-carb­oxy­phen­yl)pyridine-2-carboxyl­ate ligand and two hy­droxy groups. One Cd(II) atom is six-coordinated by two O atoms from two ligand mol­ecules and by four...

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Detalles Bibliográficos
Autores principales: Meng, Fan-Jin, Jia, Heng-Qing, Hu, Ning-Hai, Zhou, Hua
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3515118/
https://www.ncbi.nlm.nih.gov/pubmed/23284345
http://dx.doi.org/10.1107/S1600536812042444
Descripción
Sumario:The asymmetric unit of the title polymeric complex, [Cd(2)(C(13)H(7)NO(4))(OH)(2)](n), consists of two independent Cd(II) atoms, one 5-(4-carb­oxy­phen­yl)pyridine-2-carboxyl­ate ligand and two hy­droxy groups. One Cd(II) atom is six-coordinated by two O atoms from two ligand mol­ecules and by four μ(3)-OH groups in a distorted trigonal–prismatic geometry. The other is five-coordinated by one N and two O atoms from two ligands and by two μ(3)-OH groups, forming a distorted square-pyramidal geometry. The two independent Cd(II) atoms are connected by the ligand mol­ecules and the OH groups into a three-dimensional framework. O—H⋯O hydrogen bonds between the OH groups and the carboxyl­ate O atoms are observed.