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Poly[di-μ(3)-hydroxy[μ(4)-5-(4-carboxyphenyl)pyridine-2-carboxylato-κ(5) N,O (2):O (2′):O (4):O (4′)]dicadmium]
The asymmetric unit of the title polymeric complex, [Cd(2)(C(13)H(7)NO(4))(OH)(2)](n), consists of two independent Cd(II) atoms, one 5-(4-carboxyphenyl)pyridine-2-carboxylate ligand and two hydroxy groups. One Cd(II) atom is six-coordinated by two O atoms from two ligand molecules and by four...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3515118/ https://www.ncbi.nlm.nih.gov/pubmed/23284345 http://dx.doi.org/10.1107/S1600536812042444 |
Sumario: | The asymmetric unit of the title polymeric complex, [Cd(2)(C(13)H(7)NO(4))(OH)(2)](n), consists of two independent Cd(II) atoms, one 5-(4-carboxyphenyl)pyridine-2-carboxylate ligand and two hydroxy groups. One Cd(II) atom is six-coordinated by two O atoms from two ligand molecules and by four μ(3)-OH groups in a distorted trigonal–prismatic geometry. The other is five-coordinated by one N and two O atoms from two ligands and by two μ(3)-OH groups, forming a distorted square-pyramidal geometry. The two independent Cd(II) atoms are connected by the ligand molecules and the OH groups into a three-dimensional framework. O—H⋯O hydrogen bonds between the OH groups and the carboxylate O atoms are observed. |
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